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RSC - Dalton Trans. latest articles



RSC - Dalton Trans. latest articles



Last Build Date: Thu, 21 Sep 2017 19:21:53 Z

Copyright: Copyright (c) The Royal Society of Chemistry
 



Exploiting the Energetic Potential of 1,2,4-Oxadiazole Derivatives: Combining the Benefits of 1,2,4-Oxadiazole Framework with Various Energetic Functionalities
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03320F, Paper
Chao Yan, Kangcai Wang, Tianlin Liu, Hongwei Yang, guangbing cheng, Qinghua Zhang
A series of 1,2,4-oxadiazole-derived energetic compounds were successfully synthesized using the 1,2,4-oxadiazole-3-chloroxime as a versatile starting material. These energetic compounds were fully characterized by NMR spectroscopy, IR spectroscopy, and elemental...
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Nickel-Ruthenium-Based Complexes as Biomimetic Models of [NiFe] and [NiFeSe] Hydrogenases for Dihydrogen Evolution
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02631E, Paper
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Gamze Gezer, Sjoerd Verbeek, Maxime A Siegler, Elisabeth Bouwman
The two heterodinuclear nickel-ruthenium complexes [Ni(xbSmS)RuCp(PPh3)]PF6 and [Ni(xbSmSe)RuCp(PPh3)]PF6 (H2xbSmS = 1,2-bis(4-mercapto-3,3-dimethyl-2-thiabutyl)benzene, H2xbSmSe = 1,2,-bis(2-thiabutyl-3,3-dimethyl-4-selenol)benzene, Cp = cyclopentadienyl) were synthesized as biomimetic models of [NiFe] and [NiFeSe] hydrogenases. The X-ray structural...
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Isolation and Characterization of Tetranuclear Pt-Fe---Fe-Pt Intermediate en Route to the Trinuclear Pt-Fe-Pt Cluster
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02583A, Paper
Kazuhiro Uemura, Masahiro Taoka
An intermediate compound, [{PtFe(piam)2(NH3)2(OCH3)}2([small mu ]-OCH3)2](ClO4)2[middle dot](1, piam = pivalamidate), in the synthetic process to form [Pt2Fe(piam)4(NH3)4](ClO4)3 (2) by mixing cis-[Pt(piam)2(NH3)2][middle dot]2H2O and iron sources was successfully isolated and characterized by single-crystal X-ray analysis....
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Two-photon spectroscopy of tungsten(0) arylisocyanides using nanosecond-pulsed excitation

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02632C, Paper
Kana Takematsu, Sara A. M. Wehlin, Wesley Sattler, Jay R. Winkler, Harry B. Gray
The two-photon absorption (TPA) cross sections ([small delta]) for tungsten(0) arylisocyanides (W(CNAr)6) were determined in the 800-1000 nm region using two-photon luminescence (TPL) spectroscopy.
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Allowing the direct interaction of N-aryl [small alpha]-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03226A, Communication
Niccolo Bartalucci, Marco Bortoluzzi, Tiziana Funaioli, Fabio Marchetti, Guido Pampaloni, Stefano Zacchini
BREAKING THE RULE! N-(2,6-diisopropylphenyl) [small alpha]-diimines, known to be robust ligands in coordination chemistry, convert into quinoxalinium cations by reaction with WCl6 in mild conditions.
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Synthesis and Characterization of Uranium(IV) Tetrachloro Complexes in Bis-Pyrazolylpyridine Ligand Environments
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02947K, Paper
Jana Korzekwa, Andreas Scheurer, Frank Heinemann, Karsten Meyer
Starting from dimethyl 2,6-pyridinedicarboxylate (3), four pyridine-bridged bispyrazole ligands 1a[space]-[space]1d were generated in a two- or three-step synthesis sequence and further treated with UCl4 to yield the corresponding novel mononuclear...
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Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03105J, Frontier
Pierre Thuery, Jack Harrowfield
A survey is given of recent original structural results on heterometallic species incorporating uranyl ions, particularly with carboxylate ligands.
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Coexistence of long-range antiferromagnetic order and slow relaxation of the magnetization in the first lanthanide complex of a 1,2,4-benzotriazinyl radical

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02766D, Communication
Ian S. Morgan, Akseli Mansikkamaki, Mathieu Rouzieres, Rodolphe Clerac, Heikki M. Tuononen
We have synthesised and characterised the compound Dy(1)(tbacac)3 (2), the first lanthanide complex of a new coordinating 1,2,4-benzotriazinyl radical (1).
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Catalyst-free room-temperature iClick reaction of molybdenum(II) and tungsten(II) azide complexes with electron-poor alkynes: structural preferences and kinetic studies

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03096G, Paper
Paul Schmid, Matthias Maier, Hendrik Pfeiffer, Anja Belz, Lucas Henry, Alexandra Friedrich, Fabian Schonfeld, Katharina Edkins, Ulrich Schatzschneider
The azide complexes [M([small eta]3-allyl)(N3)(bpy)(CO)2] with M = Mo, W smoothly react in a [3 + 2] cycloaddition reaction with electron-poor alkynes.
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The role of ligand redox non-innocence in ring-opening polymerization reactions catalysed by bis(imino)pyridine iron alkoxide complexes

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03067C, Paper
K. R. Delle Chiaie, A. B. Biernesser, M. A. Ortuno, B. Dereli, D. A. Iovan, M. J. T. Wilding, B. Li, C. J. Cramer, J. A. Byers
The reactivity of iron-based ring opening polymerization catalysts is compared when the catalyst is in three different oxidation states.
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Bowl shaped deformation in a planar aromatic polycycle upon reduction. Li and Na separated dianions of the aromatic polycycle 5,6:11,12-di-o-phenylene-tetracene

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03039H, Paper
T. Wombacher, R. Goddard, C. W. Lehmann, J. J. Schneider
Reduction of the PAH LDOPT with lithium metal in DME results in a massive deformation in the resulting dianionic [small pi]-perimeter.
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SbVO4 nanoparticles synthesized via three facile one-pot methods: controllable morphologies and superhydrophobic coatings

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03188B, Paper
Ximeng Liu, Xiaojuan Yang, Feng Li, Taohai Li, Wei Cao
Novel superhydrophobic surfaces were fabricated by easy drop-casting of SbVO4 nanoparticles (synthesized via three different facile methods) on glass, exhibiting excellent superhydrophobicity whether under corrosion environment or not.
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A reactive oxygen species-generating, cyclooxygenase-2 inhibiting, cancer stem cell-potent tetranuclear copper(II) cluster

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02789C, Communication
C. Lu, K. Laws, A. Eskandari, K. Suntharalingam
Tetranuclear copper(II) complexes containing multiple diclofenac and Schiff base moieties, 1-4, are shown to kill bulk cancer cells and cancer stem cells (CSCs) with low micromolar potency.
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The fluorescence properties of tiara like structural thiolated palladium clusters

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02836A, Paper
Jishi Chen, Yanze Pan, Zonghua Wang, Peng Zhao
A series of tiara like structural Pdn(SR)2n (5 [less-than-or-equal] n [less-than-or-equal] 20) nanoclusters exhibit emission at 620 nm with excitation at around 268 nm. Their emission is due to ligand to metal charge transfer.
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A cobalt(II)heteroarylalkenolate precursor for homogeneous Co3O4 coatings by atomic layer deposition

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02757E, Paper
Mehtap Buyukyazi, Thomas Fischer, Penmgei Yu, Mariona Coll, Sanjay Mathur
We present a robust approach to prepare conformal Co3O4 nanocoatings on high aspect ratio structures from a new cobalt metalorganic complex.
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Two nanoscale Nb containing polyoxometalates based on {P2W15Nb3O62} clusters and chromium cations

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02737K, Communication
Peng Huang, Xin-Long Wang, De-Qing He, Hai-Yang Wu, Chao Qin, Meng Du, Chao Lai, Zhong-Min Su
We have introduced mixed-addenda Nb/W polyoxometalates as a new class of materials for lithium-ion batteries and demonstrated their capability as anode materials with good cycling stability.
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Synthesis, characterization and catalytic epoxidation properties of lanthanide-stabilized peroxoisopolytungstates

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02471A, Paper
Jipeng Guo, Yanjun Niu, Lanying Song, Qiaofei Xu, Jingkun Lu, Pengtao Ma, Dongdi Zhang, Chao Zhang, Jingyang Niu, Jingping Wang
A series of new lanthanide-containing peroxoisopolyoxotungstates, K6Na4[H32{Ln4(WO4)(H2O)16[W7O22(O2)2]4}3][middle dot]105H2O [Ln = CeIII (1), NdIII (2), SmIII (3), TbIII (4), ErIII (5)], have been successfully synthesized and structurally characterized.
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Cytotoxicity and Mechanism of Action of New Multinuclear Scaffold AuIII, PdII Pincer Complexes Containing Bis(diphenylphosphino) Ferrocene/Non-Ferrocene Ligand
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02887C, Paper
Leila Tabrizi, Hossein Chiniforoshan
The new multinuclear gold(III), palladium(II) pincer complexes containing bis(diphenylphosphino) ferrocene/non-ferrocene ligands of formula [(L)Au([small mu ]2-[small eta]2-CS3)Pd(dppf)](PF6)2, 1, and [(L)Au([small mu ]2-[small eta]2-CS3)Pd(dppe)](PF6)2, 2 (HL=5-methoxy-1,3-bis (1-methyl-1H-benzo[d]imidazol-2-yl)benzene, dppf = 1,1[prime or minute]-bis(diphenylphosphino)ferrocene, and dppe = bis(diphenylphosphino)ethane) have been synthesized...
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Synthesis of Metastable Chromium Carbide Nanomaterials and their Electrocatalytic Activity for the Hydrogen Evolution Reaction
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT01404J, Paper
Samantha M Schmuecker, Dale Albert Clouser, Theodore J Kraus, Brian Leonard
Transition metal carbides including chromium, molybdenum, and tungsten are of particular interest as renewable energy catalysts due to their low cost and abundance. While several single metal carbide systems form...
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Chemistry and Radiochemistry of Arsenic, Rhenium and Rhodium Isotopes Relevant to Radiopharmaceutical Applications: Development of High Specific Activity Radionuclides for Imaging and Treatment
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02407J, Paper
Yutian Feng, Tim E. Phelps, Valerie Carroll, Fabio Gallazzi, Gary Sieckman, Timothy J. Hoffman, Charles L Barnes, Alan R. Ketring, Heather M. Hennkens, Silvia Jurisson
The chemistry and radiochemistry of high specific activity radioisotopes of arsenic, rhenium and rhodium are presented in this review with emphasis on University of Missouri activities over the past several...
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KLi3Fe(C2O4)3: a perovskite-like compound with 1:3 ordering at both A and B sites
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03468G, Communication
Wenjiao Yao, Yuanyuan Guo, Philip Lightfoot
KLi3Fe(C2O4)3 adopts a perovskite-like structure with 1:3 ordering of (Li,Fe) on the B-site and (K,vacancy) on the A-site; there are no previous examples of this type of cation ordering in...
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Ru-Os dyads based on a mixed bipyridine-terpyridine bridging ligand: modulation of the rate of energy transfer and pH-induced luminescence switching in the infrared domain

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02192E, Paper
Manoranjan Bar, Dinesh Maity, Sourav Deb, Shyamal Das, Sujoy Baitalik
Ru-Os dyads exhibit intramolecular energy transfer from Ru to the Os-center and pH-induced luminescence switching in the infrared domain.
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Chemosensor for micro to nano-molar detection of Ag+ and Hg2+ ions in pure aqueous media and its applications in cell imaging
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02524F, Paper
Jitendra P. Nandre, Samadhan R. Patil, Suban K Sahoo, Chullikkattil P. Pradeep, Andrei Churakov, Fabiao Yu, Lingxin Chen, Carl Redshaw, Ashok Anandrao Patil, Umesh Daga Patil
The pyridine substituted thiourea derivative PTB-1 was synthesized and characterized by spectroscopic techniques as well as by single crystal X-ray crystallography. The metal ion sensing ability of PTB-1 was explored...
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A porous copper-organic framework with intersecting channels and gas adsorption properties
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03339G, Paper
zhenzhen Xue, Di Zhang, Jie Pan, Song-De Han, Jinhua Li, Guo-Ming Wang
Solvothermal reaction of CuI with a bifunctional organic ligand 3,5-pyridinedicarboxylic acid (H2pdc) afforded a novel heterovalent copper-organic framework, [(CuI2I2)CuII4(pdc)4(H2O)4][round bullet, filled]4DMSO (1) (DMSO = dimethyl sulfoxide). Compound 1 was structurally characterized by...
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A micrometer-sized europium(III)-organic framework for selective sensing of Cr2O72- anion and picric acid in water system
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02531A, Paper
Hongming He, Si-Hang Chen, De-Yu Zhang, Rui Hao, Chao Zhang, En-Cui Yang, Xiao-Jun Zhao
A micrometer-sized europium(III)-organic framework with asymmetric binuclear metal subunits extended by 4,5-dichlorophthalaten (DCPA), [Eu2(H2O)(DCPA)3]n, was easily obtained by reverse microemulsion method. The framework exhibits good dispersibility, excellent thermal and environmental...
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An interesting 1,4,2,5-dioxadiazine-furazan system: structural modification by incorporating versatile functionalities
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02098H, Paper
Qiong Yu, Guangbin Cheng, Xuehai Ju, Chunxu Lu, Qiuhan Lin, Hongwei Yang
The 1,4,2,5-dioxadiazine ring is combined with two furazan rings. Interestingly, the structure of the 1,4,2,5-dioxadiazine-furazan system can be modificated by incorporating versatile functionalities. The N-trinitroethylamino functionalization derivatives and energetic salts...
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Visualization of stable ferritin complexes with palladium, rhodium and iridium nanoparticles detected by their catalytic activity in native polyacrylamide gels
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02818K, Communication
Vladimir Pekarik, Marie Peskova, Roman Guran, Zbynek Heger, Jiri Novacek, Vojtech Adam, Jitender Kumar, Konstantinos Tripsianes
Reductive discoloration of azo dye Congo red catalyzed by noble metal nanoparticles was used to visualize protein-metal complexes in native polyacrylamide gels after counterstaining with Coomassie blue. This technique was...
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Pseudo electron-deficient organometallics: limited reactivity towards electron-donating ligands

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02827J, Paper
Anais Pitto-Barry, Alexandru Lupan, Markus Zegke, Thomas Swift, Amr A. A. Attia, Rianne M. Lord, Nicolas P. E. Barry
This work presents the unusual reactivity of a family of electron-deficient half-sandwich metal complexes.
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Silica-Polydopamine Core-Shell Self-Confined Template for Ultra-Stable Hollow Pt Anchored N-Doped Carbon Electrocatalyst
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03021E, Paper
Guo-Chang Li, Jian Li, Ziwei Zhou, Congling Li, chao cai, bingkun guo, Rodney Dewayne Priestley, Lei Han, Rui Liu
We present the use of silica-polydopamine (SiO2@PDA) core-shell nanoparticles (NPs) as self-confined templates to fabricate ultra-stable hollow Pt anchored N-doped carbon nanospheres (Pt/HN-C). SiO2@PDA nanospheres were fabricated by a facile...
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Structural diversity in Cu(I) complexes of the PNP ligand: from pincer to binuclear coordination modes and their effects upon the electrochemical and photophysical properties.
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02244A, Paper
Pablo Arce, Cristian M. Vera , Dayra L. Escudero, Juan Guerrero, Alexander G. Lappin, Allen Grayson Oliver, Danilo H. Jara, G Ferraudi, Luis A. Lemus
A set of new copper (I) complexes is synthesized and characterized using a labile PNP pincer ligand (PNP=N,N'-bis(diphenylphosphine)-2,6-diaminopyridine). A homoleptic Cu(I) complex [Cu(PNP-[small kappa]P1:[small kappa]N1)2]+, (1), was prepared, and taking advantage of...
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A new strongly paramagnetic cerium containing microporous MOF for CO2 fixation under ambient conditions
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02040F, Paper
Sabuj Kanti Das, Sauvik Chatterjee, Subhajit Bhunia, Abhishake Mondal, Partha Mitra, Vandana Kumari, Anirban Pradhan, Asim Bhaumik
Metal organic frameworks (MOFs) bearing multicarboxylate linkers is very demanding in designing a robust heterogeneous catalyst. A new microporous Ce(III) based metal organic framework (Ce2NDC3) has been synthesized under solvothermal...
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Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03074F, Communication
Alex J. Plajer, Kevin Bold, Felix J. Rizzuto, Raul Garcia-Rodriguez, Tanya K. Ronson, Dominic S. Wright
The unsymmetrical PIII/PV cyclodiphosphazane [(S[double bond, length as m-dash])(H)P([small mu ]-NtBu)2PNHtBu] provides entry into the mixed chalgogenide dianion [(S)P([small mu ]-NtBu)2P(Se)NtBu]2-, and unique insight into the mechanisms of cis/trans isomerism in phosph(III)- and phosph(V)-azanes.
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Long-range magnetic ordering in a metal-organic framework based on octanuclear nickel(II) clusters

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02889J, Communication
Jun-Li Wang, Yan Bai, Hui Pan, Guang-Shui Zheng, Dong-Bin Dang
A beautiful 3D nickel(II)-organic framework possessing one type of rare polyhedral cage has been synthesized based on H3BTC and bpp ligands. Long-range magnetic ordering is observed in the framework.
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Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: new insights into the reaction mechanism

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Dalton Trans., 2017, 46,12257-12262
DOI: 10.1039/C7DT03154H, Paper
Hossein Ghari, Yifan Li, Roohollah Roohzadeh, Paola Caramenti, Jerome Waser, Alireza Ariafard
New insights into the mechanism of gold-catalyzed domino reactions with hypervalent iodine reagents revealed by computation and confirmed by experiments.
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Fluorite-type coordination compound as iodide ion conductor: crystal structure and ionic conductivity

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02458D, Paper
Xin Chen, Chen Xue, Shao-Xian Liu, Jian-Lan Liu, Zhi-Yuan Yao, Xiao-Ming Ren
Fluorite-type coordination compound [Mn(en)3]I2, as a new type of iodide ion conductor, shows higher ion conductivity.
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Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02700A, Paper
Antonio Martinez, Sonia Moreno-Blazquez, Antonio Rodriguez-Dieguez, Alberto Ramos, Rafael Fernandez-Galan, Antonio Antinolo, Fernando Carrillo-Hermosilla
Simple ZnEt2 is an efficient catalyst for the addition of terminal alkynes to carbodiimides, through amidinate complexes, and consecutive isocyanate addition and intramolecular cyclohydroamination.
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A convenient access to N-phosphonio-substituted NHC metal complexes [M = Ag(I), Rh(I), Pd(II)]

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Dalton Trans., 2017, 46,12293-12305
DOI: 10.1039/C7DT02759A, Paper
Idir Benaissa, Rachid Taakili, Noel Lugan, Yves Canac
NHC Pd(II) complexes featuring a propyl bridge were ionized by the introduction of a phosphonium moiety, which may coordinate to the metal center or remain pendant.
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Mg doped Li2FeSiO4/C nanocomposites synthesized by the solvothermal method for lithium ion batteries

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT03177G, Paper
Ajay Kumar, O. D. Jayakumar, Jagannath, Parisa Bashiri, G. A. Nazri, Vaman. M. Naik, Ratna Naik
Despite having the same carbon content, Li2Fe0.99Mg0.01SiO4/C delivered the highest initial discharge capacity and also exhibited the best rate capability and cycle stability.
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Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02017A, Paper
Alexey N. Bilyachenko, Alexander A. Korlyukov, Anna V. Vologzhanina, Victor N. Khrustalev, Alena N. Kulakova, Jerome Long, Joulia Larionova, Yannick Guari, Marina S. Dronova, Ulyana S. Tsareva, Pavel V. Dorovatovskii, Elena S. Shubina, Mikhail M. Levitsky
The ability of the polynuclear cage metallasilsesquioxane [(PhSiO1.5)12(CuO)4(NaO0.5)4(n-BuOH)8] with a globular structure to act as a stable building block of hybrid materials with respect to the substitution of sodium cations and terminal butanol molecules was confirmed.
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Synthesis and in vivo anticancer evaluation of poly(organo)phosphazene-based metallodrug conjugates

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Dalton Trans., 2017, 46,12114-12124
DOI: 10.1039/C7DT01767G, Paper
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Carmen M. Hackl, Beatrix Schoenhacker-Alte, Matthias H. M. Klose, Helena Henke, Maria S. Legina, Michael A. Jakupec, Walter Berger, Bernhard K. Keppler, Oliver Bruggemann, Ian Teasdale, Petra Heffeter, Wolfgang Kandioller
Macromolecular drug conjugates: Polymer conjugation reduces local side effects and tumor growth in vivo.
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Towards ionic liquids with tailored magnetic properties: bmim+ salts of ferro- and antiferromagnetic CuII3 triangles

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Dalton Trans., 2017, 46,12263-12273
DOI: 10.1039/C7DT02472J, Paper
Athanassios K. Boudalis, Guillaume Rogez, Benoit Heinrich, Raphael G. Raptis, Philippe Turek
With proper selection of counteraction and pH control, CuII3-pyrazolate anions can form a ferromagnetic low-melting solid, or an antiferromagnetic viscous paste.
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Urea-glass preparation of titanium niobium nitrides and subsequent oxidation to photoactive titanium niobium oxynitrides

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Dalton Trans., 2017, 46,12081-12087
DOI: 10.1039/C7DT03077K, Paper
James J. Brancho, Aaron D. Proctor, Shobhana Panuganti, Bart M. Bartlett
Titanium niobium oxynitrides (TiNbON) are an attractive category of potential photocatalysts, but strategies for preparing them remain limited.
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Facile synthesis of photoluminescent inorganic-organic hybrid carbon dots codoped with B and N: towards an efficient lubrication additive

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Dalton Trans., 2017, 46,12306-12312
DOI: 10.1039/C7DT02389H, Paper
Yunxiao Zhang, Tao Cai, Wangji Shang, Dan Liu, Qiang Guo, Shenggao Liu
An inorganic-organic carbon dots consisting of an ionic liquid moiety inserted in the carbon skeleton has been synthesized and verified to be a high-performance anti-wear and friction-reducing lubricant additives in poly(ethylene glycol)(PEG).
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Fluorescent mesogenic boron difluoride complexes derived from heterocyclic benzoxazoles

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Dalton Trans., 2017, 46,12274-12283
DOI: 10.1039/C7DT02937C, Paper
Ya-Wen Chen, Gene-Hsiang Lee, Chung K. Lai
One new series of boron difluoride complexes 1 derived from heterocyclic benzoxazoles 2 was reported, and their mesomorphic and optical properties were also investigated.
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NI(II) phosphine and phosphide complexes supported by a PNP-pyrrole pincer ligand

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Dalton Trans., 2017, 46,12125-12131
DOI: 10.1039/C7DT02784B, Paper
Julie A. Kessler, Vlad M. Iluc
Deprotonation of cationic nickel phosphines led to isolation of the corresponding phosphide or phopshinomethyl complexes.
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Mono-BHT heteroleptic magnesium complexes: synthesis, molecular structure and catalytic behavior in the ring-opening polymerization of cyclic esters

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Dalton Trans., 2017, 46,12132-12146
DOI: 10.1039/C7DT02469J, Paper
I. E. Nifant'ev, A. V. Shlyakhtin, V. V. Bagrov, M. E. Minyaev, A. V. Churakov, S. G. Karchevsky, K. P. Birin, P. V. Ivchenko
Dimeric BHT-alkoxy magnesium complexes are able to catalyze ROP of lactones and lactides by the binuclear mechanism.
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Facile activation of alkynes with a boraguanidinato-stabilized germylene: a combined experimental and theoretical study

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Dalton Trans., 2017, 46,12339-12353
DOI: 10.1039/C7DT01950E, Paper
Jiri Boserle, Grigory Zhigulin, Petr Stepnicka, Filip Horky, Milan Erben, Roman Jambor, Ales Ruzicka, Sergey Ketkov, Libor Dostal
A comprehensive study of the activation of various alkynes by boraguanidinato-stabilized germylene is presented.
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Reactivity of the geminal phosphinoborane tBu2PCH2BPh2 towards alkynes, nitriles, and nitrilium triflates

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Dalton Trans., 2017, 46,12284-12292
DOI: 10.1039/C7DT02570J, Paper
Evi R. M. Habraken, Lars C. Mens, Martin Nieger, Martin Lutz, Andreas W. Ehlers, J. Chris Slootweg
The reactivity of the geminal phosphinoborane tBu2PCH2BPh2 towards terminal alkynes, nitriles and nitrilium salts is investigated.
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Ag3I[(MoO3)2(IO3)2]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag+) and anion (I-)

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Dalton Trans., 2017, 46,12320-12327
DOI: 10.1039/C7DT02795H, Paper
Chang-Yu Meng, Pei Zhang, Rong-Fang Wang, Lei Geng
A new noncentrosymmetric compound Ag3I[(MoO3)2(IO3)2] has been hydrothermally synthesized and characterized.
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Methylation of Ir(III)-tetrazolato complexes: an effective route to modulate the emission outputs and to switch to antimicrobial properties

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Dalton Trans., 2017, 46,12328-12338
DOI: 10.1039/C7DT02352A, Paper
Valentina Fiorini, Ilaria Zanoni, Stefano Zacchini, Anna Luisa Costa, Alejandro Hochkoeppler, Valerio Zanotti, Anna Maria Ranieri, Massimiliano Massi, Alessandra Stefan, Stefano Stagni
The conversion of neutral to cationic Ir(III) tetrazolato complexes enables the red-shift of emission and the switch-on of antibacterial properties against Gram(+) D. radiodurans.
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A 4-dimethylaminobenzoate-functionalized Ti6-oxo cluster with a narrow band gap and enhanced photoelectrochemical activity: a combined experimental and computational study

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Dalton Trans., 2017, 46,12313-12319
DOI: 10.1039/C7DT02650A, Paper
Hai-Ting Lv, Ying Cui, Yu-Min Zhang, Hua-Min Li, Guo-Dong Zou, Rui-Huan Duan, Jun-Tao Cao, Qiang-Shan Jing, Yang Fan
The D-[small pi]-A structured dye 4-dimethylaminobenzoate (DMABA) functionalized Ti6-oxo cluster exhibits a remarkably reduced band gap of [similar]2.5 eV.
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Direct transformation of 2-acetylpyridine oxime esters into [small alpha]-oxygenated imines in an Ir(III) complex

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Dalton Trans., 2017, 46,12032-12035
DOI: 10.1039/C7DT02528A, Communication
Hiroyuki Takahashi, Shintaro Kodama, Youichi Ishii
2-Acetylpyridine oxime esters are transformed into the corresponding [small alpha]-oxygenated imines in an Ir(III) complex under mild conditions.
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Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes

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Dalton Trans., 2017, 46,12027-12031
DOI: 10.1039/C7DT03099A, Communication
Nga Kim T. Ho, Beate Neumann, Hans-Georg Stammler, Vitor H. Menezes da Silva, Daniel G. Watanabe, Ataualpa A. C. Braga, Rajendra S. Ghadwal
Direct C2-arylation of NHCs to C2-arylated imidazolium salts (III) is achieved using Ni-catalysis. The dinuclear Ni(I) species I undergoes oxidative addition with ArX to give the Ni(II) intermediate II. Reductive elimination delivers the arylation product III and regenerates the catalyst I.
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The impact of ionic liquids on the coordination of anions with solvatochromic copper complexes

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Dalton Trans., 2017, 46,12185-12200
DOI: 10.1039/C7DT02372C, Paper
O. Kuzmina, N. H. Hassan, L. Patel, C. Ashworth, E. Bakis, A. J. P. White, P. A. Hunt, T. Welton
Traditionally weakly associating anions demonstrate a stronger than expected level of coordinating ability within ILs.
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Volatile heterometallics: structural diversity of Pd-Pb [small beta]-diketonates and correlation with thermal properties

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Dalton Trans., 2017, 46,12245-12256
DOI: 10.1039/C7DT02843A, Paper
Vladislav V. Krisyuk, Iraida A. Baidina, Natalia A. Kryuchkova, Vladimir A. Logvinenko, Pavel E. Plyusnin, Ilya V. Korolkov, Galina I. Zharkova, Asiya E. Turgambaeva, Igor K. Igumenov
Volatile heterobimetallics based on Pb(hfac)2 as a host material and a range of Pd(II) [small beta]-diketonates have been studied to trace the influence of the nature of initial monometallic complexes on the structure, composition and thermal properties.
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Ring expansion of a ring expanded carbene

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Dalton Trans., 2017, 46,12015-12018
DOI: 10.1039/C7DT03046K, Communication
(image) Open Access
Lucia Garcia, Khalidah H. M. Al Furaiji, David J. D. Wilson, Jason L. Dutton, Michael S. Hill, Mary F. Mahon
Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature and ring opening on heating.
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A crystalline AlPO4-5 intermediate: designed synthesis, structure, and phase transformation

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Dalton Trans., 2017, 46,12209-12216
DOI: 10.1039/C7DT02772A, Paper
Cong Lin, Jian Li, Fengjuan Pan, Yifang Zhao, Le Xu, Yanquan Yang, Xin Du, Xiaohuan Lin, Fuhui Liao, Jianhua Lin, Tao Yang, Junliang Sun
A crystalline AlPO4-5 intermediate with phase transformability is designedly synthesized, providing new thoughts for the crystallization mechanism studies.
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Synthesis, characterisation and in vitro cytotoxicity of mixed ligand Pt(II) oxadiazoline complexes with hexamethylenetetramine and 7-nitro-1,3,5-triazaadamantane

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Dalton Trans., 2017, 46,12226-12238
DOI: 10.1039/C7DT02406A, Paper
Stefanie Sieste, Irina Lifincev, Nina Stein, Gabriele Wagner
The synthesis, spectroscopic and DFT-computational characterisation of trans-Pt(II) oxadiazoline complexes is described. Some are more cytotoxic in vitro than cisplatin with the human cancer cell lines HeLa and A549.
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Water-stable Eu-MOF fluorescent sensors for trivalent metal ions and nitrobenzene

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Dalton Trans., 2017, 46,12201-12208
DOI: 10.1039/C7DT02590D, Paper
Honghong Li, Yanbing Han, Zhichao Shao, Na Li, Chao Huang, Hongwei Hou
We have synthesized two functionalized Eu-MOFs and found that the MOFs are promising luminescent probes for selectively sensing metal ions (Fe3+ and Cr3+) and nitrobenzene.
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Direct self-focusing synthesis of monodisperse [Au8(PPh3)7]2+ nanoclusters

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Dalton Trans., 2017, 46,12239-12244
DOI: 10.1039/C7DT02657A, Paper
Ting Huang, Li Huang, Yong Jiang, Fengchun Hu, Zhihu Sun, Guoqiang Pan, Shiqiang Wei
Direct synthesis of atomically monodisperse Au8 nanoclusters via the self-focusing process during NaBH4 reduction of Au(PPh3)2Cl.
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Multicomponent equiatomic rare earth oxides with a narrow band gap and associated praseodymium multivalency

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Dalton Trans., 2017, 46,12167-12176
DOI: 10.1039/C7DT02077E, Paper
Abhishek Sarkar, Christoph Loho, Leonardo Velasco, Tiju Thomas, Subramshu S. Bhattacharya, Horst Hahn, Ruzica Djenadic
Phase pure multinary rare earth oxides, containing multivalent praseodymium, have a narrow band gap and a high level of oxygen vacancies.
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The influence of functional groups on the ethylene polymerization performance of silsesquioxane-supported Phillips-type catalysts

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Dalton Trans., 2017, 46,12158-12166
DOI: 10.1039/C7DT02492D, Paper
Ryuki Baba, Ashutosh Thakur, Patchanee Chammingkwan, Minoru Terano, Toshiaki Taniike
A series of silsesquioxane-supported Phillips-type molecular catalysts for ethylene polymerization were synthesized by introducing various functional groups in proximity to monoalkylated Cr(III).
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Synthesis and characterisation of new tripodal lanthanide complexes and investigation of their optical and magnetic properties

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Dalton Trans., 2017, 46,12177-12184
DOI: 10.1039/C7DT02556D, Paper
Alexander R. Craze, Xin-Da Huang, Isaac Etchells, Li-Min Zheng, Mohan M. Bhadbhade, Christopher E. Marjo, Jack K. Clegg, Evan G. Moore, Maxim Avdeev, Leonard F. Lindoy, Feng Li
The neutral complexes of type [EuL], [GdL] and [DyL] incorporating a heptadentate tripodal ligand were synthesized and their optical and magnetic properties have been investigated.
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New homoleptic bis(pyrrolylpyridiylimino) Mg(II) and Zn(II) complexes as catalysts for the ring opening polymerization of cyclic esters via an "activated monomer" mechanism

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Dalton Trans., 2017, 46,12217-12225
DOI: 10.1039/C7DT02445B, Paper
Ilaria D'Auria, Consiglia Tedesco, Mina Mazzeo, Claudio Pellecchia
The reaction of MgBu2 and ZnEt2 or Zn{N[Si(CH3)3]2}2 with a tridentate monoanionic pyrrolylpyridiylimino [N-,N,N] proligand gave homoleptic species, as exclusive products, in high yields.
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NIR emission and luminescent sensing of a lanthanide-organic framework with Lewis basic imidazole and pyridyl sites

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Dalton Trans., 2017, 46,12106-12113
DOI: 10.1039/C7DT02745A, Paper
Le-Hui Liu, Xing-Tai Qiu, Yong-Jiang Wang, Qing Shi, Yan-Qiong Sun, Yi-Ping Chen
Three luminescent lanthanide-organic frameworks, [Ln(Himdc)(ina)(H2O)]n, consist of a 3D microporous lanthanide carboxylate ([Eu(COO)3]n) framework and imidazole and pyridyl sites for the luminescent sensor.
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Crown ether complexes of actinyls: a computational assessment of AnO2(15-crown-5)2+ (An = U, Np, Pu, Am, Cm)

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Dalton Trans., 2017, 46,12354-12363
DOI: 10.1039/C7DT02825C, Paper
Shu-Xian Hu, Wan-Lu Li, Liang Dong, John K. Gibson, Jun Li
Computational characterization of AnO22+-(15-crown-5) complexes (An = U, Np, Pu, Am, and Cm) reveals actinyl insertion coordination to crown ether.
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Multimodal imaging and photothermal therapy were simultaneously achieved in the core-shell UCNR structure by using single near-infrared light

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Dalton Trans., 2017, 46,12147-12157
DOI: 10.1039/C7DT02791E, Paper
Chen Wang, Liangge Xu, Jiating Xu, Dan Yang, Bin Liu, Shili Gai, Fei He, Piaoping Yang
Core-shell nanostructures consisting of plasmonic materials and lanthanide-doped upconversion nanoparticles (UCNPs) show promising applications in theranostics including bio-imaging, diagnosis and therapy.
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Superior lithium-ion insertion/extraction properties of a novel LiFePO4/C/graphene material used as a cathode in aqueous solution

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Dalton Trans., 2017, 46,12019-12026
DOI: 10.1039/C7DT02341C, Communication
Wenyuan Duan, Mingshu Zhao, Junfang Shen, Suixin Zhao, Xiaoping Song
Herein, olivine LiFePO4 covered with graphene and carbon layers is prepared via a sol-gel method, followed by calcination, and the resultant composite is used as a cathode material in aqueous rechargeable lithium-ion batteries (ARLBs).
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A route to robust thioether-functionalized MOF solid materials displaying heavy metal uptake and the ability to be further oxidized

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Dalton Trans., 2017, 46,12036-12040
DOI: 10.1039/C7DT02334K, Communication
Guo-Wei Xiao, Teng-Fei Chen, Xin-Zhan Sun, Hui Guo, Zhong-Feng Li, Yu-Heng Deng, Chong-Qing Wan
A facile and mild solvent-assisted ligand exchange method was developed as an alternative strategy to achieve thioether-based MOFs, and their oxidized forms, that were able to take up heavy metals from solutions and capture CO2.
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The pKa value of the proximal water molecule trans to a high-valent MnV[double bond, length as m-dash]O porphyrin: towards the control of reactivity by pH

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Dalton Trans., 2017, 46,12088-12094
DOI: 10.1039/C7DT01829K, Paper
Laurie Saint-Germes, Laure Bar, Jerome Dejeu, Nicolas Spinelli, Eric Defrancq, Genevieve Pratviel
In water, the protonation state of the proximal water molecule of a high-valent manganese-oxo porphyrin could be controlled by pH. While in interaction with DNA the porphyrin was able to cleave DNA, only when the proximal water molecule was in the form of a hydroxyl group.
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Structural variations in (CuL)2Ln complexes of a series of lanthanide ions with a salen-type unsymmetrical Schiff base(H2L): Dy and Tb derivatives as potential single-molecule magnets

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Dalton Trans., 2017, 46,12095-12105
DOI: 10.1039/C7DT02061A, Paper
Prithwish Mahapatra, Soumavo Ghosh, Naoki Koizumi, Takuya Kanetomo, Takayuki Ishida, Michael G. B. Drew, Ashutosh Ghosh
Five heterometallic Cu2Ln complexes (Ln = Gd, Tb, Dy, Ho and Er) have been synthesized using asymmetric Schiff base ligand. Among these, Cu2Tb and Cu2Dy complexes show field induced SMM behaviour.
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Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal-organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles

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Dalton Trans., 2017, 46,12010-12014
DOI: 10.1039/C7DT02155K, Communication
Clement Falaise, Christophe Volkringer, Raynald Giovine, Benedicte Prelot, Marielle Huve, Thierry Loiseau
Aluminium-based metal-organic framework MIL-100 was utilized for the capture of actinide ([UO2]2+, Th4+) and lanthanide (Nd3+) cations.
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Controlling ligand binding for tunable and switchable catalysis: cation-modulated hemilability in pincer-crown ether ligands

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Dalton Trans., 2017, 46,11987-12000
DOI: 10.1039/C7DT02156A, Perspective
Alexander J. M. Miller
The development of cation-responsive "pincer-crown ether" complexes featuring tunable hemilability is reviewed in the context of switchable and tunable catalysis.
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Antiproliferative activity of ([small eta]6-arene)ruthenacarborane sandwich complexes against HCT116 and MCF7 cell lines

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Dalton Trans., 2017, 46,12067-12080
DOI: 10.1039/C7DT02027A, Paper
Marta Gozzi, Benedikt Schwarze, Menyhart-Botond Sarosi, Peter Lonnecke, Dijana Draca, Danijela Maksimovic-Ivanic, Sanja Mijatovic, Evamarie Hey-Hawkins
The [([small eta]6-arene)RuC2B9H11] complexes (arene = p-cymene (2), biphenyl (3) and 1-Me-4-COOEt-C6H4 (4)) show cytotoxic activity and excellent selectivity towards specific tumour cells.
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Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues

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Dalton Trans., 2017, 46,12041-12052
DOI: 10.1039/C7DT02145C, Paper
Geng Bang Jin, Christos D. Malliakas, Jian Lin
Three new thorium phosphides synthesized through CuI-mediated solid-state reactions exhibit more diverse ion-ion interactions than those in U pnictides.
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N-Heterocyclic carbene adducts of the heavier group 15 tribromides. Normal to abnormal isomerism and bromide ion abstraction

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Dalton Trans., 2017, 46,12053-12066
DOI: 10.1039/C7DT02431B, Paper
Jordan B. Waters, Qien Chen, Thomas A. Everitt, Jose M. Goicoechea
The reactivity of the heavier group 15 tribromides, SbBr3 and BiBr3, towards 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) is described.
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Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: synthesis and applications

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Dalton Trans., 2017, 46,12005-12009
DOI: 10.1039/C7DT02126G, Communication
Tapas Ghatak, Shani Drucker, Natalia Fridman, Moris S. Eisen
Novel thorium complexes containing six- and seven-membered rings iminato moieties are disclosed. The complexes are highly active for the Tishchenko and cross-Tishchenko reaction.
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A general strategy to add diversity to ruthenium arene complexes with bioactive organic compounds via a coordinated (4-hydroxyphenyl)diphenylphosphine ligand

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Dalton Trans., 2017, 46,12001-12004
DOI: 10.1039/C7DT02062G, Communication
Lorenzo Biancalana, Lucinda K. Batchelor, Alice De Palo, Stefano Zacchini, Guido Pampaloni, Paul J. Dyson, Fabio Marchetti
Ruthenium arene complexes obtained by direct esterification of a phosphine ligand with bioactive carboxylic acids show enhanced cytotoxicity compared to the respective precursors.
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Fabrication of Mesoporous Ba0.5Sr0.5Co0.8Fe0.2O3-[small delta] Perovskite as a Low-Cost and Efficient Catalyst for Oxygen Reduction
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03082G, Paper
Xiangzhi Cui, Ryan O'Hayre, Svitlana Pylypenko, Linlin Zhang, Liming Zeng, Xiaohua Zhang, Zile Hua, Hangrong Chen, Jianlin Shi
A precious metal-free cathode catalyst, mesoporous Ba0.5Sr0.5Co0.8Fe0.2O3-[small delta] (m-BSCF) with well crystallized perovskite framework and porous structure (pore size of ~10 nm) has been synthesized by a one-step co-nanocasting method. The...
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Syntheses, Structures and Properties of Metal Phosphates Pb2Mg(PO4)2, Pb4Zn8(PO4)8 and [small alpha]-BaZn2(PO4)2
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03055J, Paper
Pan Xiaobo, Ming Wen, He Guijie, Hongyi Li, Dianzeng Jia
Pb2Mg(PO4)2, Pb4Zn8(PO4)8 and [small alpha]-BaZn2(PO4)2 have been synthesized by the standard solid-state reaction and the structures were determined by single crystal X-ray diffraction for the first time. Pb2Mg(PO4)2, Pb4Zn8(PO4)8 and [small alpha]-BaZn2(PO4)2...
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Solid state structures and properties of free-base 5, 10, 15-triphenylcorrole (TPCor) anions obtained by deprotonation and reduction. Effective magnetic coupling of spins in (Cp*2Cr+)(H+){H2TPCor(.2-)}.C6H4Cl2
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02901B, Paper
Dmitri V. Konarev, Dmitry R. Karimov, Salavat S. Khasanov, Alexander F. Shestakov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Rimma N. Lyubovskaya
Reduction of 5,10,15-triphenylcorrole (H3TPCor) with decamethylchromocene yields (Cp*2Cr+)(H+)(H2TPCor[round bullet, filled]2-).C6H4Cl2 (1). It is accompanied by deprotonation of H3TPCor and the formation of planar radical H2Cor(.2-) dianions. Complex 1 manifests a band at...
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New Mo(IV) complex with the pentadentate (N3O2) Schiff-base ligand: The first non-cyanide pentagonal-bipyramidal paramagnetic 4d complex
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02912H, Communication
Vladimir Sergeevich Mironov, Tamara A. Bazhenova, Yuriy Manakin, Konstantin Lyssenko, Artem Dmitrievich Talantsev, Eduard B. Yagubskii
Heptacoordinate complex [MoIV(DAPBH)Cl2] (H2DAPBH is 1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene))dibenzohydrazine) has been synthesized and characterized structurally and magnetically. It exhibits a slightly distorted pentagonal bipyramidal geometry and reveals paramagnetic behavior resulting from two unpaired...
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Covalently Immobilized Ionic Liquids on Single Layer Nanosheets for Heterogeneous Catalysis Applications
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT01510K, Paper
Yingjie Zhou, Jingjing Liu, Rongcai Huang, Meng Zhang, Min Xiao, Yuezhong Meng, Luyi Sun
Ionic liquids (ILs) have attracted significant attention because of their unique chemical and physical properties. Immobilization of ILs on solid materials helps increase their efficiency and facilitate their recycling. In...
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Series anionic host coordination polymers based on azoxybenzene carboxylate: structures, luminescence and magnetic properties
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02974H, Paper
Xun Feng, Nan Guo, Haipeng Chen, Helin Wang, Xin Chen, Lingyun Yue, Seik Weng Ng, Xinfang Liu, Lufang Ma, Liya Wang
Series of coordination polymers {[Ln(aobtc)(H2O)4][round bullet, filled]Hbipy[round bullet, filled]H2O}n (H4aobtc = azoxybenzene - 2, 2', 3, 3'-tetracarboxylic acid, bipy = 4,4'-bipyridine, and Ln = Sm(1), Eu(2), Gd(3), Tb(4), Dy(5), Er(6) have been afforded and...
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Bis(silylenyl)-substituted ferrocene-stabilized 6-arene iron(0) complexes: synthesis, structure and catalytic application
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03301J, Paper
Matthias Driess, Marcel Philip Luecke, Digvijay Porwal, Arseni Kostenko, Yupeng Zhou, Shenglai Yao, Matthias Keck, Christian Limberg, Martin Oestreich
Reaction of FeX2(thf)n (X = Cl n = 1.5, Br n = 2) with the chelating 1,1' bis(silylenyl)-substituted ferrocene ligand SiFcSi A (Fc = ferrocendiyl, Si = PhC(NtBu)2Si:) furnishes the...
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Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02565C, Paper
Jani Moilanen, Akseli Mansikkamaki, Manu Lahtinen, Fu-Sheng Guo, Elina Kalenius, Richard Layfield, Liviu F. Chibotaru
The synthesis and structural characterization of two benzoquinone-bridged dinuclear rare-earth complexes [BQ(MCl2[middle dot]THF3)2] (BQ = 2,5-bisoxide-1,4-benzoquinone; M = Y (1), Dy (2)) are described. Of these reported metal complexes, the dysprosium...
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Fluoroquinolones as imaging agents for bacterial infection

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT01189J, Perspective
Syed Ali Raza Naqvi, Karl Drlica
Three ways to radioactively label fluoroquinolones are available, thereby creating multiple options for developing a diagnostic for deep-seated bacterial infection.
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A new glance on the R2MGe6 (R = rare earth metal, M=another metal) compounds. An experimental and theoretical study of R2PdGe6 germanides
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02686B, Paper
Riccardo Freccero, PAVLO SOLOKHA, Davide M Proserpio, Adriana Saccone, Serena De Negri
The R2PdGe6 series (R = rare earth metal) was structurally characterized, and results achieved were extended for a comprehensive study on the R2MGe6 (M = another metal) compounds, employing a...
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Ring Contraction of Metallabenzooxirene to Metal Carbonyl Complexes - A Comparative Study with the Wolff Rearrangement of Oxirene and Benzooxirene
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02911J, Paper
Chakkittakandiyil Anusha, Susmita De, Pattiyil Parameswaran
A detailed quantum mechanical study on the role of transition metal fragments towards the epoxidation reaction of metallabenzynes (1M, M = Fe, Ru, Os) to give metallabenzyne epoxide or metallabenzooxirene...
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Self-assembly of p-chiral supramolecular phosphines on rhodium and a direct evidence for Rh-catalyst-substrate interaction in asymmetric hydrogenation
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02923C, Paper
Vijay Koshti, Anirban Sen, Dinesh R Shinde, Samir H Chikkali
Supramolecular phosphine derived catalysts are known to provide high enantioselectivity in asymmetric transformation such as hydrogenation, but direct evidence unraveling the role of secondary interactions are largely missing. As a...
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Comparison of the Ca2+ complexing properties of isosaccharinate and gluconate - is gluconate a reliable structural and functional model of isosaccharinate?
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT03120C, Paper
Csilla Dudas, Bence Kutus, Eva Boszormenyi, Gabor Peintler, Zoltan Kele, Istvan Palinko, Pal Sipos
The calcium complexation and acid-base properties of [small alpha]-D-isosaccharinate (Isa-) in neutral and in (hyper)alkaline solutions have been investigated via potentiometric titrations, multinuclear NMR, ESI-MS and quantum chemical calculations. Isa- is...
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Tuning the gate-opening pressure and particle size distribution of the switchable metal-organic framework DUT-8(Ni) by controlled nucleation in a micromixer
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02809A, Paper
Hiroki Miura, Volodymyr Bon, Irena Senkovska, Sebastian Ehrling, Satoshi Watanabe, Masaaki Ohba, Stefan Kaskel
Controlled nucleation in a micromixer and further crystal growth was used to synthesize Ni2(2,6-ndc)2dabco (2,6-ndc - 2,6-naphthalenedicarboxylate, dabco - 1,4-diazabicyclo[2.2.2]octane), also termed DUT-8(Ni) (DUT = Dresden University of Technology) with...
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Metal-organic frameworks with 1,4-di(1H-imidazol-4-yl)benzene and varied carboxylate ligands for selectively sensing Fe(III) Ion and ketone molecules
Dalton Trans., 2017, Accepted Manuscript
DOI: 10.1039/C7DT02981K, Paper
Zhi-Qiang Liu, Yue Zhao, Xiu-Du Zhang, Yan-Shang Kang, Qingyi Lu, Mohammad Azam, Saud I Al-Resayes, Wei-Yin Sun
Four new metal-organic frameworks (MOFs) [Zn(L)(bpdc)][round bullet, filled]1.6H2O (1), [Co(L)(bpdc)][round bullet, filled]H2O (2), [Ni3(L)2(bptc)2(H2O)10][round bullet, filled]2H2O (3) and [Cd2(L)(Hbptc)2] (4) were achieved by reactions of corresponding metal salt with mixed organic ligands of 1,4-di(1H-imidazol-4-yl)benzene (L) and...
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A ruthenium water oxidation catalyst containing a bipyridine glycoluril ligand

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02485A, Paper
Vishwanath S. Mane, Avinash S. Kumbhar, Randolph P. Thummel
A mononuclear ruthenium complex [Ru(tpy)(bpg)H2O]2+ bearing a bipyridine glycoluril ligand (bpg) = 4b,5,7,7a-tetrahydro-4b,7a-nepiminomethan-oimino-6H-imidazo[4,5-f][1,10]phenanthroline-6,13-dione acts as a robust water oxidation catalyst (WOC) at pH = 1 using Ce(IV) as a sacrificial oxidant.
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Sulfonato-imino copper(II) complexes: fast and general Chan-Evans-Lam coupling of amines and anilines

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02260C, Communication
V. Hardouin Duparc, F. Schaper
A simple coordination complex allows Chans-Evans-Lam arylations of a wide variety of amines and anilines without optimization of reaction conditions.
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Site preferences in hetero-metallic [Fe9-xNix] clusters: a combined crystallographic, spectroscopic and theoretical analysis

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02930F, Paper
Anastasia N. Georgopoulou, Karrar Al-Ameed, Athanassios K. Boudalis, Dimitrios F. Anagnostopoulos, Vassilis Psycharis, John E. McGrady, Yiannis Sanakis, Catherine P. Raptopoulou
The distribution of Fe(II) and Ni(II) over two distinct metal sites in [Fe9-xNix] clusters is studied by X-ray crystallography, Mossbauer and XRF spectroscopies, and DFT calculations.
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Cobalt(II) containing liquid metal salts for electrodeposition of cobalt and electrochemical nanoparticle formation

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02604H, Paper
Jeroen Sniekers, Pieter Geysens, Joao C. Malaquias, Tom Vander Hoogerstraete, Luc Van Meervelt, Jan Fransaer, Koen Binnemans
Cobalt(II) containing ionic liquids were used as electrolytes for the electrodeposition of cobalt thin films and cobalt nanoparticles.
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Mononuclear salen-gallium complexes for iso-selective ring-opening polymerization (ROP) of rac-lactide

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02730C, Paper
David Specklin, Christophe Fliedel, Frederic Hild, Samir Mameri, Lydia Karmazin, Corinne Bailly, Samuel Dagorne
Mononuclear salen-supported Ga amido and alkoxide complexes, structurally characterized herein, mediate the controlled and iso-selective polymerization of rac-lactide.
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Thermal conductivity of a perovskite-type metal-organic framework crystal

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02927F, Communication
Wilarachchige D. C. B. Gunatilleke, Kaya Wei, Zheng Niu, Lukasz Wojtas, George Nolas, Shengqian Ma
The thermal conductivity of a perovskite-type MOF crystal has been investigated for the first time.
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Single-ion magnetism in seven-coordinate YbIII complexes with distorted D5h coordination geometry

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Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT02461D, Paper
Dong-Qing Wu, Dong Shao, Xiao-Qin Wei, Fu-Xing Shen, Le Shi, Yi-Quan Zhang, Xin-Yi Wang
Two seven-coordinate compounds of pentagonal bipyramidal YbIII centers exhibiting field-induced slow magnetic relaxation were characterized structurally and magnetically.
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