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RSC - Dalton Trans. latest articles



RSC - Dalton Trans. latest articles



Last Build Date: Tue, 20 Feb 2018 01:40:08 Z

Copyright: Copyright (c) The Royal Society of Chemistry
 



Exploit the Benefit of S0-->T1 Excitation in Triplet-Triplet Annihilation Upconversion to Attain Large Anti-Stokes Shifts: Tuning the Triplet State Lifetime of a Tris(2,2'-Bipyridine) Osmium(II) Complex
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04803C, Paper
Dongyi Liu, Yingjie Zhao, Zhijia Wang, Kejing Xu, Jianzhang Zhao
Os(II) complexes are particular interesting for triplet-triplet annihilation (TTA) upconversion, due to the strong direct S0-->T1 photoexcitation, as in this way, energy loss is minimized and large anti-Stokes shift can...
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Trapping of Transient, Heavy Pnictogen-Centred Biradicals
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00487K, Communication
Axel Schulz, Jonas Bresien, Alexander Hinz, Alexander Villinger
Since the heavy biradicals [E(-NTer)]2 (E = Sb, Bi) are only of fleeting existence in solution, they were generated in situ and quenched by [2+2] addition reactions utilizing alkynes such...
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Reactant or Reagent? Oxidation of H2 at Electronically Distinct Nickel-Thiolate Sites [Ni2([small micro]-SR)2]+ and [Ni-SR]+
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00275D, Paper
Felix Koch, Andreas Berkefeld
The chemical bond between a Lewis acidic metal and a Bronsted/Lewis-basic sulphur donor provides M-S structures with functional properties that are relevant for a variety of processes such as the...
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General strategies for effective capture and separation of noble gases by metal-organic frameworks
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00030A, Frontier
Hao Wang, Jing Li
In this frontier article we provide a brief overview of recent progress on capture and separation of noble gases by microporous metal-organic framework-based adsorbents, with an emphasis on xenon and...
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Retention of selenium by calcium aluminate hydrate (AFm) phases under strongly-reducing radioactive waste repository conditions
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04824F, Paper
Henar Rojo, Andreas C. Scheinost, Barbara Lothenbach, Andreas Laube, Erich Wieland, Jan Tits
Safety assessment studies of future nuclear waste repositories carried out in many countries predict selenium-79 to be a critical radionuclide due to its presence as anions in three relevant oxidation...
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Synthesis and Characterization of Thallium-Salen Derivatives for use as Underground Fluid Flow Tracers
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04121G, Paper
Timothy J Boyle, Diana Perales, Jessica Rimsza, Todd M Alam, Daniel M. Boye, Jeremiah M Sears, Jeffery Greathouse, Richard Kemp
A pair of thallium salen derivatives was synthesized and characterized for potential use as monitors (or taggants) or as models for Group 13 complexes for subterranean fluid flows. These precursors...
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Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn)
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04561A, Paper
Javier Brugos, Javier A. Cabeza, Pablo Garcia-Alvarez, Enrique Perez-Carreno, Diego Polo
The non-donor-stabilized PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4 (1) has been prepared by treating SnCl2 with Li2(NCH2PtBu2)2C6H4. All attempts to synthesize the analogous PSiP silylene by reduction of the (previously unknown) silanes...
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The peculiarities of complex formation and energy transfer processes in lanthanide complexes with 2-(tosylamino)-benzylidene-N-benzoylhydrazone
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04387B, Paper
Anton D Kovalenko, Ivan S. Bushmarinov, Anatoly D Burlov, Leonid Lepnev, Elena G. Ilina, Valentina V. Utochnikova
Depending on the local excess of lanthanide ion (Ln = Lu, Yb, Er, Dy, Tb, Gd, Eu, Nd) or 2-(tosylamino)-benzylidene-N-benzoylhydrazone (H2L), lanthanide complexes, containing either mono-deprotonated ligand (Ln(HL)2X, X =...
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Direct formation of Au(III) acetyl, alkoxyl and alkynyl functionalities via halide free tricationic Au(III) precursors
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04675H, Paper
Jason Laurence Dutton, Robert Corbo, Mohammad Al Bayer, Neville Hall
A novel synthetic approach for the synthesis of gold(III) acetato, alkoxolato and alkynyl complexes was developed via the reactivity of gold(III) trications containing the N,N-chelating ligand 2,2'-bipyridine and N,N,N-chelating ligand...
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Water Molecule Induced Reversible Single-Crystal-to-Single-Crystal Transformation Between Two Trinuclear Fe(II) Complexes with Different Spin Crossover Behaviour
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00318A, Paper
Wen-Bin Chen, Yan-Cong Chen, Meng Yang, Mingliang Tong, Wen Dong
A 4-amino-1,2,4-triazole (NH2-trz) based linear trinuclear Fe(II) complex of [Fe3(NH2-trz)6(SCN)4(H2O)2](SCN)2[middle dot]H2O (1) has been hydrothermally synthesized by the reaction of NH2-trz ligand with FeSO4. A single crystal of complex 1 is...
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Ultra-high aspect ratio hybrid materials: the role of organic guest and synthesis method

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04312K, Communication
G. V. Manohara, Li Li, Andrew Whiting, H. Chris Greenwell
Hybrid layered double hydroxide materials with high aspect ratio have been prepared by slow hydrolysis of metal hydroxides with hydrophobic anions.
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A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00146D, Paper
Gabriel Brunet, Elena Sebastiao, Tomasz G. Witkowski, Ilia Korobkov, Bulat Gabidullin, Muralee Murugesu
A nitrogen-rich ligand is employed as a scaffold for lanthanide ions, leading to clear SMM-like behaviour and two well-isolated modes of magnetic relaxation.
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Redox-responsive UCNPs-DPA conjugated NGO-PEG-BPEI-DOX for imaging-guided PTT and chemotherapy for cancer treatment

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04093H, Paper
Arif Gulzar, Jiating Xu, Liangge Xu, Piaoping Yang, Fei He, Dan Yang, Guanghui An, Mohd Bismillah Ansari
The disulfide bond (-S-S-) is an enormously valuable functional group in a variety of chemical and biological agents that display effective reactivity or biological activities (e.g., antitumor activities).
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Synthesis of Silyl Iron Hydride via Si-H Activation and its Double Catalytic Application in Hydrosilylation of Carbonyl Compounds and Dehydration of Benzamides
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00289D, Paper
shishuai ren, shangqing xie, tingting zheng, Yangyang Wang, benjing xue, shilu xu, Hongjian Sun, Xiaoyan Li, olaf fuhr, Dieter Fenske
Hydrido silyl iron complex (2) was obtained via the activation of Si-H bond of bidentate silyl ligand o-Ph2P(C6H4)SiMe2H (1) by Fe(PMe3)4. 2 showed excellent to good catalytic activity in both...
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Quadratic and Cubic Hyperpolarizabilities of Nitro-phenyl/-naphthalenyl/-anthracenyl Alkynyl Complexes
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00155C, Paper
Jun Du, Mahesh Kodikara, Graeme Moxey, Mahbod Morshedi, Adam Barlow, Cristobal Quintana, Genmiao Wang, Rob Stranger, Chi Zhang, Marie Cifuentes, Mark G Humphrey
The 1-nitronaphthalenyl-4-alkynyl and 9-nitroanthracenyl-10-alkynyl complexes [M](C[identical with]C-4-C10H6-1-NO2) ([M] = trans-[RuCl(dppe)2] (6), trans-[RuCl(dppm)2] (7), Ru(PPh3)2(5-C5H5) (8), Ni(PPh3)(5-C5H5) (9), Au(PPh3) (10)) and [M](C[identical with]C-10-C14H8-9-NO2) ([M] = trans-[RuCl(dppe)2] (11), trans-[RuCl(dppm)2] (12), Ru(PPh3)2(5-C5H5) (13), Ni(PPh3)(5-C5H5) (14),...
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Spectroelectrochemical studies of a ruthenium complex containing the pH sensitive 4,4'-dihydroxy-2,2'-bipyridine ligand
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04554A, Paper
Erin J. Viere, Ashley E. Kuhn, Margaret H. Roeder, Nicholas A. Piro, William S. Kassel, Timothy Dudley, Jared J. Paul
Attaining high oxidation states at the metal center of transition metal complexes is a key design principle for many catalytic processes. One way to support high oxidation state chemistry is...
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CuO/CeO2 catalyst for glycerol selective conversion to lactic acid
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04340F, Paper
Ruben Palacio, Sebastian Torres, Sebastien Royer, Anne-Sophie Mamede, Diana Lopez, Diana Hernandez
Ceria supported copper oxide catalysts were produced by deposition-precipitation method, at high copper loading (up to > 25 wt%). These materials demonstrated excellent properties for the glycerol selective conversion to...
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Multi-molecular emission of a cationic Pt(II) complex through hydrogen bonding interactions

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00314A, Paper
Kaho Yamaguchi, Kazuma Yamawaki, Takuya Kimura, Junpei Kuwabara, Takeshi Yasuda, Yoshinobu Nishimura, Takaki Kanbara
Upon the photoexcitation of a hydrogen-bonded Pt complex, a stacked structure is formed in the excited state, exhibiting dimer emission.
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Facile one-pot green synthesis of Au-Ag alloy nanoparticles using sucrose and their composition-dependent photocatalytic activity for the reduction of 4-nitrophenol
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT03850J, Paper
Li Sun, Yuechao Yin, Fa Wang, Wenxian Su, Lixin Zhang
Au-Ag alloy nanoparticles (NPs) less than 10 nm in size were synthesized using sucrose as reductant and surfactant. Au-Ag alloy NPs with homogeneous composition were continuously obtain by changing the...
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Water soluble derivatives of platinum carbonyl Chini clusters: synthesis, molecular structures and cytotoxicity of [Pt12(CO)20(PTA)4]2- and [Pt15(CO)25(PTA)5]2-
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00228B, Paper
Lucinda Kate Batchelor, Beatrice Berti, Cristiana Cesari, Iacopo Ciabatti, Paul Dyson, Cristina Femoni, Maria Carmela Iapalucci, Matteo Mor, Silvia Ruggieri, Stefano Zacchini
The reactions of [Pt3n(CO)6n]2- (n = 2-5) homoleptic Chini-type clusters with increasing amounts of 1,3,5-triaza-7-phosphaadamantane (PTA) result in the stepwise substitution of one terminal CO ligand per Pt3 triangular units...
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Upconversion in photodynamic therapy: plumbing the depths

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00087E, Frontier
Michael R. Hamblin
Upconversion photodynamic therapy uses sequential multiphoton absorption by transition metal nanoparticles (NaYF4/Yb3+/Er3+) to allow FRET excitation of traditional visible light-absorbing photosensitizers by deeply penetrating near infrared light (810 nm or 980 nm).
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Adsorptive removal of organic dyes from aqueous solution by a Zr-based metal-organic framework: effects of Ce(III) doping

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00217G, Paper
Ji-Min Yang, Rong-Jian Ying, Chun-Xiang Han, Qi-Tu Hu, Hui-Min Xu, Jian-Hui Li, Qiang Wang, Wei Zhang
Ce(III)-doped UiO-66 nanocrystals exhibited better dye adsorption performance than pristine UiO-66, showing the advantages of high stability and excellent porosity.
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Self-assembly of singlet-emitting double-helical silver dimers: the curious coordination chemistry and fluorescence of bisquinolylpyridone

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04744D, Paper
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Charlotte M. A. Farrow, Geoffrey R. Akien, Nathan R. Halcovitch, James A. Platts, M. P. Coogan
The previously unreported ligand 2,6-bis(2-quinolyl)-4(1H)-pyridone spontaneously assembles into double helical dimers with Ag+ - its fluorescence is BLUESHIFTED upon complexation.
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Enhanced glucose sensing based on a novel composite CoII-MOF/Acb modified electrode

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00296G, Paper
Yuanyuan Wen, Wei Meng, Chen Li, Lei Dai, Zhangxing He, Ling Wang, Ming Li, Jing Zhu
A novel electrochemical sensor composed of a composite of CoII-MOF/acetylene black exhibits enhanced sensing behavior for glucose detection.
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A three-dimensional (time, wavelength and intensity) functioning fluorescent probe for the selective recognition/discrimination of Cu2+, Hg2+, Fe3+ and F- ions

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04785A, Communication
Qin Ruan, Lan Mu, Xi Zeng, Jiang-Lin Zhao, Li Zeng, Zhen-Min Chen, Cai Yang, Gang Wei, Carl Redshaw
A new probe for the selective recognition/discrimination of Cu2+, Hg2+, Fe3+ and F- ions by measuring their response time, wavelength and fluorescence intensity.
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Distinct photophysical behaviour and transport of cell-impermeable [Ru(bpy)2dppz]2+ in live cells using cucurbit[7]uril as a delivery system

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04230B, Paper
Meenakshi N. Shinde, Soniya S. Rao, Shridhar P. Gejji, Anupa A. Kumbhar
We have successfully demonstrated the delivery of a cell-impermeable [Ru(bpy)2dppz]2+ complex across the cell membrane in live cells using a cucurbit[7]uril molecular container.
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Reversible phase transition and switchable dielectric behaviors triggered by rotation and order-disorder motions of crowns

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00003D, Paper
Yi Liu, Hai-Tao Zhou, Shao-Peng Chen, Yu-Hui Tan, Chang-Feng Wang, Chang-Shan Yang, He-Rui Wen, Yun-Zhi Tang
Compound 1 shows apparent step-like dielectric changes near the phase transition, which are triggered by the synergetic rotation motion of 18-C-6 crown ether cycles and hexafluorophosphate anions.
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A novel 3-D cuprous iodide polymer with a high Cu/I ratio

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00054A, Communication
Hong Xiao, Jian Zhou, Xing Liu, Hongping Xiao, Rute A. S. Ferreira, Luis D. Carlos, Lianshe Fu
The interconnection of rare 1-D cationic aggregates [CuI3I2+]n and anionic bi-tetrazolate bridges leads to the formation of a novel 3-D cuprous iodide polymer with a Cu/I ratio as high as 3, which shows unusually thermochromic luminescent properties.
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Kinetics and mechanism of the chromium(VI) catalyzed decomposition of hypochlorous acid at elevated temperature and high ionic strength

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00120K, Paper
Jozsef Kalmar, Maria Szabo, Nina Simic, Istvan Fabian
The decomposition of hypochlorous acid was studied under industrially relevant conditions (6.0 M NaClO3, 80 [degree]C). Chromium(VI) catalyzes the decomposition and the catalytically active form is CrO42-. A detailed kinetic model is proposed for the process.
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Remarkable structural effects on the complexation of actinides with H-phosphonates: a combined experimental and quantum chemical study

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04902A, Paper
Aditi Chandrasekar, Brahmmananda Rao C.V.S., Mahesh Sundararajan, Tapan K. Ghanty, N. Sivaraman
Strikingly novel effects on pH-modulated actinide extraction by branched H-phosphonates are investigated by solvent extraction combined with DFT.
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Diastereoselective synthesis, structure and reactivity studies of ferrocenyloxazoline gold(I) and gold(II) complexes

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00109J, Paper
Julia Holz, Marta Ayerbe Garcia, Wolfgang Frey, Felix Krupp, Rene Peters
The first asymmetric synthesis of planar chiral ferrocenyl Au(I) and Au(II) complexes, their molecular/supramolecular structures, and their reactivity are reported.
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The mechanism of manganese dissolution on Li1.6Mn1.6O4 ion sieves with HCl

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00033F, Paper
Aolei Gao, Zhenhua Sun, Shaopeng Li, Xinjuan Hou, Huiquan Li, Qisheng Wu, Xinguo Xi
Tetravalent manganese in the surface was converted to bivalent manganese after acquiring sufficient electrons from inner trivalent manganese.
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Facile synthesis of a cationic-doped [Ca24Al28O64]4+(4e-) composite via a rapid citrate sol-gel method

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04543C, Paper
Karim Khan, Ayesha Khan Tareen, Sayed Elshahat, Ashish Yadav, Usman Khan, Minghui Yang, Luigi Bibbo, Zhengbiao Ouyang
We have presented a general strategy for the synthesis of novel nanocrystalline [Ca24Al28O64]4+(4e-) composite and the corresponding materials doped with Si/Ga cations.
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Fluorescent antitumor titanium(IV) salen complexes for cell imaging

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04828A, Communication
Avia Tzubery, Naomi Melamed-Book, Edit Y. Tshuva
First live cell imaging using florescent salen Ti(IV) complexes, which are cytotoxic and inactive, both entering the cell but with different subcellular accumulations.
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Evaluation of a Novel Platinum(II)Based AIE Compound-Encapsulated MesoporousSilica Nanoparticles for Cancer Theranostic Application
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04232A, Paper
saleem pasha, Leena Fageria, Inamur Rahaman Laskar, Rajdeep chowghury, Aniruddha Roy, Nigam P Rath, Claudia Climent, Pere Alemany
Advanced biomedical research has established that cancer is a multifactorial disorder which is highly heterogeneous in nature and responds differently to different treatment modalities, due to which constant monitoring of...
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Carbodiphosphorane-based nickel pincer complexes and their (de)protonated analogues: dimerisation, ligand tautomers and proton affinities
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04930G, Paper
Leon Maser, Jan Herritsch, Robert Langer
The reactivity patterns of carbodiphosphoranes (CDPs) as ligands are much less explored than those of isoelectronic analogues. In the current manuscript, we investigate the reactivity of the carbodiphosphorane-based PCP nickel(II)...
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Neutral and anionic zinc compounds supported by a bis(imino)phenyl NCN ligand
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00149A, Paper
Minh Tho Nguyen, Bulat Gabidullin, Georgii I. Nikonov
The new zinc complexes 2,6-(ArN=CH)2C6H3ZnBu (6) and 2,6-(ArN=CH)2C6H3ZnCl2Li(THF)3 (7), supported by a bis(imino)phenyl NCN pincer ligand were prepared (Ar=2,6-iPr2C6H3). The reaction of complex 7 with LiHBEt3 resulted in hydride transfer...
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The Taiji and Eight Trigrams Chemistry Philosophy of Chiral Iridium(III) Complexes with Triplex Stereogenic Centers
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00264A, Communication
Zhi-Ping Yan, Xu-Feng Luo, Kang Liao, Zi-Xuan Lin, Zheng-Guang Wu, Yong-Hui Zhou, Youxuan Zheng
Four novel chiral iridium(III) complexes with triplex stereogenic centers were synthesized by introducing the chiral carbon atoms into the cyclometalated and ancillary ligands, and separated into eight isomers, which are...
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Mixed-matrix materials using metal-organic polyhedra with enhanced compatibility for membrane gas separation

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00082D, Paper
Cressa Ria P. Fulong, Junyi Liu, Vincent J. Pastore, Haiqing Lin, Timothy R. Cook
The dispersion of metal-organic polyhedra into polymer thin-films exploits the host/guest capabilities of the former and the processability of the latter.
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Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT03727A, Communication
Ramona Turcas, Dora Lakk-Bogath, Gabor Speier, Jozsef Kaizer
Stoichiometric oxidation of benzaldehyde to benzoic acid or salicylic acid by [FeIV(N4Py)(O)]2+ and [FeIV(asN4Py)(O)]2+ complexes has been carried out.
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Carbon dots with efficient solid-state red-light emission through the step-by-step surface modification towards light-emitting diodes

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04579D, Paper
Jinyang Zhu, Xue Bai, Xu Chen, Zhifeng Xie, Yongsheng Zhu, Gencai Pan, Yue Zhai, Hanzhuang Zhang, Biao Dong, Hongwei Song
Carbon dots with efficient solid-state red-light emission through step-by-step surface modification.
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Base free N-alkylation of anilines with ArCH2OH and transfer hydrogenation of aldehydes/ketones catalyzed by the complexes of [small eta]5-Cp*Ir(III) with chalcogenated Schiff bases of anthracene-9-carbaldehyde

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04326K, Paper
Pooja Dubey, Sonu Gupta, Ajai K. Singh
Base free transfer hydrogenation and N-alkylation of aniline with benzyl alcohol were catalyzed by Ir(III) complexes (0.1-0.5 mol%).
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Time dependent aggregation induced emission enhancement and the study of molecular packing in closely related azo-phenol BODIPY species

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04047D, Paper
Rajendra Prasad Paitandi, Roop Shikha Singh, Bhupendra Kumar Dwivedi, Vishwa Deepak Singh, Daya Shankar Pandey
Novel fluorescent azo-phenol BODIPYs (1-3) achieved by the substituent directed fabrication of ortho (L1) and para (L2-L3) azo-phenol aldehydes.
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Intercalation of metformin into montmorillonite

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04197G, Paper
Ediana P. Rebitski, Pilar Aranda, Margarita Darder, Raffaele Carraro, Eduardo Ruiz-Hitzky
Metformin hydrochloride is spontaneously intercalated into layered silicates like montmorillonite by an ion-exchange mechanism, producing a promising controlled release system.
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A reaction of [2,6-(tBu2PO)2C6H3]NiSCH2Ph with BH3[middle dot]THF: borane mediated C-S bond cleavage

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04883A, Paper
Jie Zhang, Ting Liu, Qiang-Qiang Ma, Shujun Li, Xuenian Chen
C-S bond cleavage of the thiolato ligand of [2,6-(tBu2PO)2C6H3]NiSCH2Ph mediated by BH3 as a suitable model for the transition metal catalyzed C-S bond activation of mercaptans.
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Spectroscopy as a tool to detect multinuclear Cu(II)-triethanolamine complexes in aqueous solution

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04146B, Paper
Petra Lommens, Pieter Tack, Luce Vander Elst, Isabel Van Driessche, Laszlo Vincze, Davy Sinnaeve
The Evans method, Extended X-ray Absorption Fine Structure (EXAFS) and NMR relaxation dispersion (NMRD) spectroscopy were used to prove the existence of multimeric Cu(II)-triethanolamine species in aqueous solutions.
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Nickel(III)-mediated oxidative cascades from a thiol-bearing nickel(II) precursor to the nickel(IV) product

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04137C, Paper
Hao-Ching Chang, Sheng-Hsiang Lin, Yu-Chen Hsu, Shao-Wei Jen, Way-Zen Lee
Triggered by deprotonation, a nickel(II) complex, Ni(HPS2)2 (1) that contains two pendant thiols, is rapidly aerobically oxidized to a diamagnetic nickel(IV) complex, Ni(PS2)2 (2), through EPR-active nickel(III) intermediates.
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Ir(III) complex-based phosphorescence and electrochemiluminescence chemodosimetric probes for Hg(II) ions with high selectivity and sensitivity

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00309B, Paper
Hayoung Rhee, Taemin Kim, Jong-In Hong
Acetylacetonato Ir(III) complexes showed turn-on, turn-off, or ratiometric responses in both phosphorescence and electrochemiluminescence channels.
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Hierarchical CoO/MnCo2O4.5 nanorod arrays on flexible carbon cloth as high-performance anode materials for lithium-ion batteries

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04686C, Paper
Lianshan Ni, Wei Tang, Xiaohe Liu, Ning Zhang, Jun Wang, Shuquan Liang, Renzhi Ma, Guanzhou Qiu
Highly ordered three-dimensional hierarchical CoO/MnCo2O4.5 nanorod arrays on carbon cloth could be successfully prepared, which exhibit superior electrochemical performance.
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Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04928E, Communication
Hsiu-Jung Lin, Sean Lutz, Catherine O'Kane, Matthias Zeller, Chun-Hsing Chen, Talal Al Assil, Wei-Tsung Lee
A new design of a low-coordinate iron complex, bearing a hemilabile ligand, served as an effective hydrosilylation pre-catalyst.
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A[space]Multifunctional MOFs as Recyclable Catalyst for Fixation of CO2 with Aziridines or Epoxides and Luminescent Probe of Cr(VI)
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00254A, Paper
Chun-Shuai Cao, Ying Shi, Hang Xu, Bin Zhao
A[space]multifunctional metal-organic framework (1) containing 24-nuclear zinc nanocages displays high solvent- and pH-stability. Compound 1 can be employed as catalyst for the conversion of CO2 with aziridines or epoxides, which...
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Cationic Two-Dimensional Inorganic Network of Antimony Oxide Hydroxide for Lewis Acid Catalysis
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00188J, Communication
Jinlin Yin, Honghan Fei
We have successfully synthesized a rare example of inorganic layered materials possessing the positive charge, which is well outside the isostructural set of layered double hydroxides. The layered architecture consists...
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Synthesis of Three-Dimensional Mesoporous Cu-Al Layered Double Hydroxide/g-C3N4 Nanocomposites on Ni-foam for Enhanced Supercapacitors with Excellent Long-Term Cycling Stability
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04192F, Paper
Surya Prasad Adhikari, Ganesh Awasthi, Kyung-Suk Kim, Chan Hee Park, Cheol Sang Kim
In this paper, a novel composite of Cu-Al layered double hydroxide (LDH) nanosheets and g-C3N4 covered Ni-foam was fabricated via simple and facile two-step processes. Firstly, g-C3N4 sheets were deposited...
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One-step synthesis of nonstoichiometric TiO2 nanorods films for enhanced photocatalytic H2 evolution
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00066B, Paper
Qianqian Hu, Jian-Rong Li, Qiaohong Li, Guo Wang, Jiquan Huang, Xiao-ying Huang
The realization of one-dimensional nanostructures or Ti3+ self-doping in TiO2 photocatalysts has proven to be an effective approach for significantly improving the photocatalytic performance. Herein, a series of nonstoichiometric anatase...
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Synthesis of a new series of Ni(II), Cu(II), Co(II) and Pd(II) complexes with an ONS donor Schiff base: Crystal Structure, DFT study and catalytic investigation of Palladium and Nickel complexes towards deacylative sulfenylation of active methylene and regioselective 3-sulfenylation of indoles via thiouronium salt formation
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04635A, Paper
Namita Devi, Kuladip Sarma, Rajjakfur Rahaman, Pranjit Barman
A series of Ni(II), Cu(II), Co(II), and Pd(II) complexes have been synthesized with a chelating Schiff base ligand coordinated to metal center with ONS donor atoms. The ligand and complexes...
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Carbene Insertion into N-H Bonds with Size-Selectivity Induced by a Microporous Ruthenium-Porphyrin Metal-Organic Framework
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00434J, Paper
Lianfen Chen, Hao Cui, Yanhu Wang, Xiang Liang, Li Zhang, Cheng-Yong Su
A stable and porous porphyrinic metal-organic framework, Ru-PMOF-1(Hf), has been prepared through the self-assembly of [5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato](monocarbonyl)ruthenium (Ru(TCPP)(CO)) and HfCl4. Single-crystal X-ray diffraction analysis reveals that Ru-PMOF-1(Hf) possesses a three-dimensitional (3D)...
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Hybrid mesoporous organosilicas with molecularly imprinted cavities: towards extended exposure of active amino groups in the framework wall
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04832G, Paper
Hang Huo, Xianzhu Xu, Tingting Zhao, Yudong Li, Yanqiu Jiang, Kaifeng Lin
Hybrid molecularly imprinted mesoporous silica were synthesized by co-condensation of tetraethoxysilane and functional organosilica precursors of HQP and BPAP, in which hydroquinone (HQ) and bisphenol A (BPA) were linked as...
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Systematic dimensional reduction of the layered [small beta]-FeSe structure by solvothermal synthesis

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00025E, Paper
J. Stahl, E. Shlaen, H. Singer, D. Johrendt
Solvothermal reaction conditions control the dimensionality of iron selenide fragments.
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Combining single source chemical vapour deposition precursors to explore the phase space of titanium oxynitride thin films

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04694D, Paper
Kelly Rees, Emanuela Lorusso, Samuel D. Cosham, Alexander N. Kulak, Geoffrey Hyett
Combining single-source precursors in aerosol assisted CVD allows control of the composition of mixed anion titanium oxynitride thin films.
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Expanding the allyl analogy: accessing [small eta]3-P,B,P diphosphinoborane complexes of group 10

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00058A, Paper
Marcus W. Drover, Jonas C. Peters
Using the diphosphinoborane, (PPh2)2BMes (Mes = 2,4,6-Me3C6H3), we report the first examples of [small eta]3-P,B,P-ligated complexes using Ni(0) and Pt(II).
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Neutral ligand TIPA-based two 2D metal-organic frameworks: ultrahigh selectivity of C2H2/CH4 and efficient sensing and sorption of Cr(VI )

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00206A, Paper
Hong-Ru Fu, Ying Zhao, Zhan Zhou, Xiao-Gang Yang, Lu-Fang Ma
Two 2D porous frameworks are synthesized base on tri(4-imidazolylphenyl)amine. Compound 1 exhibits that the ultrahigh selectivity of C2H2/CH4, the highest one reported to date. Compound 2 combines the ultrahigh sensitivity and trapping for Cr2O72- in aqueous solution.
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A new series of tetrahedral Co(II) complexes [CoLX2] (X = NCS, Cl, Br, I) manifesting single-ion magnet features

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04007E, Paper
Amit Kumar Mondal, Mahesh Sundararajan, Sanjit Konar
The influence of ligand field strength on the magnetic anisotropy of a series of isostructural tetrahedral CoII complexes has been investigated by using a combined experimental and theoretical approach.
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Iron-montmorillonite clays as active sorbents for the decontamination of hazardous chemical warfare agents

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT03859C, Paper
F. Carniato, C. Bisio, C. Evangelisti, R. Psaro, V. Dal Santo, D. Costenaro, L. Marchese, M. Guidotti
Montmorillonite clay was modified to introduce iron species and acid sites in the interlayer space, aiming to obtain a catalyst with oxidising and acid properties for the degradation of chemical warfare agents.
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A 2D rhomboidal system of manganese(II) [Mn(3-MeC6H4COO)2(H2O)2]n with spin canting: rationalization of the magnetic exchange

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04380E, Paper
Beltzane Garcia-Cirera, Ramon Costa, Iberio de P. R. Moreira, Merce Font-Bardia, Montserrat Corbella
The 2D rhomboidal net of S = 5/2 spins coupled antiferromagnetically. The tilting of Mn(II) coordination octahedra induces spin canting at low temperature.
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Flexibility of components alters the self-assembly pathway of Pd2L4 coordination cages

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00112J, Paper
Shumpei Kai, Sai Prakash Maddala, Tatsuo Kojima, Shota Akagi, Koji Harano, Eiichi Nakamura, Shuichi Hiraoka
The self-assembly of a Pd2L4 cage from flexible ditopic ligands and Pd(II) ions takes place through the transient formation of submicrometre-sized sheet structures.
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A protic ionic liquid as an atom economical solution for palladium catalyzed asymmetric allylic alkylation

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04466F, Paper
Itzel Guerrero-Rios, Alfonso H. Ortiz-Ramirez, Piet W. N. M. van Leeuwen, Erika Martin
A recyclable palladium catalyst for asymmetric allylic alkylation that generates its own ionic liquid solvent.
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New hydrogen-rich ammonium metal borohydrides, NH4[M(BH4)4], M = Y, Sc, Al, as potential H2 sources
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT03926C, Paper
Agnieszka Starobrat, Tomasz Jaron, Wojciech Grochala
Three metal-ammonium borohydrides: NH4[M(BH4)4] M = Y, Sc, Al, denoted 1, 2, 3, respectively, were prepared via a low temperature mechanochemical synthesis and characterized using PXRD, FTIR and TGA/DSC/MS. The...
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Role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04728B, Perspective
Liane Marcia Rossi, Jhonatan Luiz Fiorio, Marco Aurelio Suller Garcia, Camila P Ferraz
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise engineering of nanomaterial's size, shape and surface composition, including adsorbed capping ligands, is of utmost importance to...
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Water-Soluble Platinum Nanoparticles Stabilized by Sulfonated N-Heterocyclic Carbenes: Influence of the Synthetic Approach
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00240A, Paper
Edwin A. Baquero, Simon Tricard, Yannick Coppel, Juan C. Flores, Bruno Chaudret, Ernesto de Jesus
The synthesis of metal nanoparticles (NPs) under controlled conditions in water remains a challenge in nanochemistry. Two different approaches to obtain platinum NPs, which involve the treatment of aqueous solutions...
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Mono- and dinuclear tetraphosphabutadiene ferrate anions
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04641C, Communication
Uttam Chakraborty, Julia Leitl, Bernd Muehldorf, Michael Bodensteiner, Stefan Pelties, Robert Wolf
Reduction of [CpArFe([small mu ] Br)]2 (1, CpAr = C5(C6H4-4-Et)5) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){CpArFe([small eta]4-P4)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P42- ligand....
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Six Uranyl-OrganicFrameworks with Naphthalene-Dicarboxylic Acid and Bipyridyl-Based Spacers: Syntheses, Structures, and Properties
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04909A, Paper
Wei Xu, Ya-Nan Ren, Miao Xie, Lin-Xia Zhou, Yue-Qing Zheng
A new series of uranium coordination polymers have been hydrothermally synthesized by using 1,4-naphthalene dicarboxylic acid (H2NDC), namely, (H3O)2[(UO2)2(NDC)3][round bullet, filled]H2O (1), (H2-bpp)[(UO2)2(NDC)3][round bullet, filled]EtOH[round bullet, filled]5H2O (2), (H2-bpe)2/2[(UO2)2(NDC)3][round bullet, filled]EtOH (3), (H2-bpp)[(UO2)2(NDC)3][round bullet, filled]5H2O (4), (H2-bpp)[(UO2)(HNDC)(NDC)]2[round bullet, filled]2H2O (5), and (H2-bpy)[(UO2)(NDC)2]...
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Nickel(II) complexes of 3N ligand as a model for diketone cleaving unusual nickel(II)-dioxygenases enzymes
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C7DT04739H, Communication
Ramamoorthy Ramasubramanian, Karunanithi Anandababu, Mukesh Kumar, Mayilmurugan Ramasamy
The diketone substrate bound nickel(II) complexes of 2,6-bis(1-methylbenzimidazolyl)pyridine have been synthesized and characterized as relevant active site models for unusual diketone cleaving Ni(II)-dependent enzymes Ni-ARD and DKDO. The average Ni-Npy/benzim...
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Mild and selective Pd-Ar protonolysis and C-H activation promoted by a ligand aryloxide group

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00437D, Paper
Ava Behnia, Mahmood A. Fard, Johanna M. Blacquiere, Richard J. Puddephatt
A ligand phenol/aryloxide group mediates reversible protonolysis and C-H activation at a Pd(II) centre.
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Multi-heteroatom doped carbon coated Na3V2(PO4)3 derived from ionic liquid
Dalton Trans., 2018, Accepted Manuscript
DOI: 10.1039/C8DT00062J, Paper
Lulu Zhang, Ying-Xian Zhou, Tao Li, Di Ma, Xuelin Yang
Multi-heteroatom (N, S and F) doped carbon coated Na3V2(PO4)3 (labeled as NVP/C-ILs) derived from ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM]TF2N) has been successfully fabricated. The as-prepared Na3V2(PO4)3 particles are well dispersed...
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Carbon dot-Au(I)Ag(0) assembly for the construction of an artificial light harvesting system

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C8DT00230D, Paper
Jayasmita Jana, Teresa Aditya, Tarasankar Pal
Significant transfer of energy from a carbon dot, GCD, to a fluorescent assembly, AuAgFA, paves the way to construct an artificial light harvesting system out of a GCD-AuAgFA pair.
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Synthesis, isomerisation and biological properties of mononuclear ruthenium complexes containing the bis[4(4[prime or minute]-methyl-2,2[prime or minute]-bipyridyl)]-1,7-heptane ligand

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Dalton Trans., 2018, 47,2422-2434
DOI: 10.1039/C7DT04595F, Paper
(image) Open Access
Biyun Sun, Hannah M. Southam, Jonathan A. Butler, Robert K. Poole, Alexandre Burgun, Andrew Tarzia, F. Richard Keene, J. Grant Collins
The strained complexes cis-[small beta]-[Ru(phen[prime or minute])(bb7)]2+ isomerise to the corresponding cis-[small alpha] isomers, with cis-[small alpha]-[Ru(Me4phen)(bb7)]2+ showing good antibacterial activity.
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Stepwise synthesis, characterization, DNA binding properties and cytotoxicity of diruthenium oligopyridine compounds conjugated with peptides

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04639A, Paper
Konstantinos Ypsilantis, John C. Plakatouras, Manolis J. Manos, Andreas Kourtellaris, Georgios Markopoulos, Evangelos Kolettas, Achilleas Garoufis
The conjugation of peptides to diruthenium complexes was achieved.
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Water driven formation of channels: unusual solid-state structural transformation of a heterometallic polymer

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04515H, Paper
Franco Scalambra, Manuel Serrano-Ruiz, Antonio Romerosa
We describe the synthesis of trans-{[(PTA)2CpRu-[small mu ]-CN-RuCp(PTA)2-[small mu ]-CoCl3]}n[middle dot](DMSO)n, and its crystal-to-crystal transformation to its cis isomer, with channels where water is nanoconfined, upon addition of water to the crystallization medium.
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Synthesis and properties of MoCl4 complexes with thio- and seleno-ethers and their use for chemical vapour deposition of MoSe2 and MoS2 films

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Dalton Trans., 2018, 47,2406-2414
DOI: 10.1039/C7DT04352J, Paper
(image) Open Access
Yao-Pang Chang, Andrew L. Hector, William Levason, Gillian Reid, Joshua Whittam
A new series of Mo(IV) chloride complexes with thioether and seleneoether ligands is reported; [MoCl4(nBu2E)2] (E = S, Se) function as single source precursors for the CVD of MoE2 thin films.
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Eu(III) and Cm(III) tetracarbonates - in the quest for the limiting species in solution

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Dalton Trans., 2018, 47,2393-2405
DOI: 10.1039/C7DT04836J, Paper
Rafal Janicki, Patric Lindqvist-Reis
The luminescence spectra of solids [C(NH2)3][Y:M(CO3)4][middle dot]2H2O (M = Eu, Cm) were used to establish the stoichiometry and stability of the limiting species of the aqueous Eu(III) and Cm(III) carbonate systems at different temperatures and in a broad range of ionic strengths.
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Insights into the enhanced photoelectrochemical performance of hydrothermally controlled hematite nanostructures for proficient solar water oxidation

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04536K, Paper
Jin Woo Park, Arunprabaharan Subramanian, Mahadeo A. Mahadik, Su Yong Lee, Sun Hee Choi, Jum Suk Jang
A controlled hydrothermal reaction time showed an improvement in the PEC performance of 1D [small alpha]-Fe2O3 nanorods due to an optimum aspect ratio and Sn4+ diffusion.
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The effect of metal distribution on the luminescence properties of mixed-lanthanide metal-organic frameworks

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Dalton Trans., 2018, 47,2360-2367
DOI: 10.1039/C7DT04583B, Paper
(image) Open Access
Laura K. Cadman, Mary F. Mahon, Andrew D. Burrows
The MOFs [Ln(Hodip)(H2O)][middle dot]nH2O (H4odip = 5,5[prime or minute]-oxydiisophthalic acid) have been prepared together with mixed-metal analogues, and the distribution of the metal centres has been shown to affect the luminescence properties.
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Trace level Al3+ detection in aqueous media utilizing luminescent ensembles comprising pyrene laced dynamic surfactant assembly

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Dalton Trans., 2018, 47,2352-2359
DOI: 10.1039/C7DT03401F, Paper
Nilanjan Dey, Santanu Bhattacharya
Easily synthesizable amphiphilic probes have been designed for the detection of Al3+ exclusively at mesoscopic interfaces.
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Control of nuclearity in heterometallic CuII-MnII complexes derived from asymmetric Schiff bases: structures and magnetic properties

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Dalton Trans., 2018, Advance Article
DOI: 10.1039/C7DT04766E, Paper
Prithwish Mahapatra, Sanjib Giri, Michael G. B. Drew, Ashutosh Ghosh
Among three asymmetric Schiff bases used for the synthesis of heterometallic CuII-MnII complexes, the one with N2O2 donor atoms yielded a tetranuclear and a trinuclear complex whereas two N2O3 donor ligands produced solely dinuclear complexes. The results of magnetic measurements have been justified by DFT study.
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An isolable [small beta]-diketiminato chlorosilylene

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Dalton Trans., 2018, 47,2152-2155
DOI: 10.1039/C8DT00121A, Communication
Yun Xiong, Shenglai Yao, Arseni Kostenko, Matthias Driess
The first [small beta]-diketiminate ligated chlorosilylene has been synthesised and isolated from the corresponding [small beta]-diketiminato dichlorohydrosilane through dehydrochlorination with an N-heterocyclic carbene.
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A new approach to fabricate the Mn(II)-based magnetic refrigerant through incorporation of a diamagnetic {LiO4} spacer

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Dalton Trans., 2018, 47,2143-2147
DOI: 10.1039/C7DT04820C, Communication
Jia-Wei Wu, Xue Wang, Chong-Bin Tian, Shao-Wu Du
We synthesized a new 3D MOF composed of 1D heterometallic inorganic Mn(II)-Li(I) chains in which the paramagnetic Mn(II) ions were separated by diamagnetic {LiO4} connectors. It shows a significant MCE with -[capital Delta]Sm of 30.4 J kg-1 K-1 for [capital Delta]H = 8 T at 2 K.
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A theoretical study on the mechanism of hydrogenation of carboxylic acids catalyzed by the Saito catalyst

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Dalton Trans., 2018, 47,2460-2469
DOI: 10.1039/C7DT04447J, Paper
Qianqian Lu, Jinshuai Song, Minyi Zhang, Jing Wei, Chunsen Li
The novel mechanism of carboxylic acid hydrogenation includes the hydrogenation of the carboxylic acid to an aldehyde and the hydrogenation of the aldehyde to an alcohol.
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Modifying the donor properties of tris(pyridyl)aluminates in lanthanide(II) sandwich compounds

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Dalton Trans., 2018, 47,2232-2239
DOI: 10.1039/C7DT04657J, Paper
Raul Garcia-Rodriguez, Sara Kopf, Dominic S. Wright
Changing the substituents at the 6-position of the 2-pyridyl groups in the aluminate ligands [EtAl(2-py)3]- has a large electronic and steric effect on their coordination to lanthanide(II) ions.
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Synthesis of carborane-fused carbo- and heterocycles via zirconacyclopentane intermediates

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Dalton Trans., 2018, 47,2453-2459
DOI: 10.1039/C7DT04751G, Paper
Chun-Xiao Cui, Shikuo Ren, Zaozao Qiu, Zuowei Xie
Carborane-fused zirconacyclopentane serves as an important synthon for the preparation of a variety of carborane-fused carbo- and heterocycles via insertion and transmetalation reactions.
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A yolk-shell V2O5 structure assembled from ultrathin nanosheets and coralline-shaped carbon as advanced electrodes for a high-performance asymmetric supercapacitor

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Dalton Trans., 2018, 47,2256-2265
DOI: 10.1039/C7DT04660J, Paper
Ling-Li Xing, Gang-Gang Zhao, Ke-Jing Huang, Xu Wu
Various V2O5 three-dimensional nanostructures are synthesized using a facile template-free hydrothermal method and evaluated for use as supercapacitor electrode materials.
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Synthesis and characterization of heteroleptic titanium MOCVD precursors for TiO2 thin films

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Dalton Trans., 2018, 47,2415-2421
DOI: 10.1039/C7DT04894G, Paper
Euk Hyun Kim, Min Hyuk Lim, Myoung Soo Lah, Sang Man Koo
Heteroleptic titanium alkoxides with three different ligands, i.e., [Ti(OiPr)(X)(Y)] (X = tridentate, Y = bidentate ligands), were synthesized to find efficient metal organic chemical vapor deposition (MOCVD) precursors for TiO2 thin films.
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Proton and oxygen ion conductivity in the pyrochlore/fluorite family of Ln2-xCaxScMO7-[small delta] (Ln = La, Sm, Ho, Yb; M = Nb, Ta; x = 0, 0.05, 0.1) niobates and tantalates

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Dalton Trans., 2018, 47,2376-2392
DOI: 10.1039/C7DT03912C, Paper
A. V. Shlyakhtina, K. S. Pigalskiy, D. A. Belov, N. V. Lyskov, E. P. Kharitonova, I. V. Kolbanev, A. B. Borunova, O. K. Karyagina, E. M. Sadovskaya, V. A. Sadykov, N. F. Eremeev
The tolerance factor is a good criterion to understand the structural transitions in Ln2-xCaxScMO7-[small delta] (M = Nb, Ta).
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Challenge in optoelectronic duplex switches: a red emission large-size single crystal and a unidirectional flexible thin film of a hybrid multifunctional material

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Dalton Trans., 2018, 47,2344-2351
DOI: 10.1039/C7DT04489E, Paper
Xiao Zhu, Wan-Ying Zhang, Cheng Chen, Qiong Ye, Da-Wei Fu
[N(NH2CH2CH2)3]2Mn2Cl12 is single crystal that functions as a red-light and/or dielectric switch material. This material explains the advantages of molecular materials and can be converted into transparent unidirectional films.
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Making organoruthenium complexes of 8-hydroxyquinolines more hydrophilic: impact of a novel L-phenylalanine-derived arene ligand on the biological activity

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Dalton Trans., 2018, 47,2192-2201
DOI: 10.1039/C7DT04451H, Paper
Sanam Movassaghi, Muhammad Hanif, Hannah U. Holtkamp, Tilo Sohnel, Stephen M. F. Jamieson, Christian G. Hartinger
Introduction of an L-phenylalanine-derived arene ligand leads to more hydrophilic organoruthenium(8-oxyquinolinato) anticancer agents.
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The structures, water stabilities and photoluminescence properties of two types of iodocuprate(I)-based hybrids

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Dalton Trans., 2018, 47,2306-2317
DOI: 10.1039/C7DT04558A, Paper
Guang-Ning Liu, Ruo-Yu Zhao, Hong Xu, Zi-Han Wang, Qi-Sheng Liu, Malik Zeeshan Shahid, Jin-Ling Miao, Guozhu Chen, Cuncheng Li
The effects of aromatic and aliphatic cations on the structure, water stability and photoluminescence of iodocuprate(I)-based materials were disclosed.
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Mechanistic insights into the tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium(II) complexes

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Dalton Trans., 2018, 47,2292-2305
DOI: 10.1039/C7DT04829G, Paper
Alessandro Passera, Anna Iuliano, Jesus J. Perez-Torrente, Vincenzo Passarelli
The tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium complexes has been elucidated by means of variable temperature NMR spectroscopy and DFT calculations.
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Network structure of SnO2 hollow sphere/PANI nanocomposites for electrochemical performance

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Dalton Trans., 2018, 47,2368-2375
DOI: 10.1039/C8DT00056E, Paper
Qianqian Wang, Quan Zong, Chunlei Zhang, Hui Yang, Qilong Zhang
Homogeneous SnO2 hollow spheres have been synthesized through a hydrothermal method without a template, followed by in situ polymerization of PANI.
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Rational construction of an ssa-type of MOF through pre-organizing the ligand's conformation and its exceptional gas adsorption properties

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Dalton Trans., 2018, 47,2444-2452
DOI: 10.1039/C7DT04867J, Paper
Yao Wang, Minghui He, Zhi Tian, Haoyan Zhong, Lisha Zhu, Yingying Zhang, Xiaoping Zhang, De-Li Chen, Yabing He
A ligand conformation-controlled assembly strategy has been successfully employed to construct a copper-based MOF with the desired ssa-type topology, which exhibits exceptional C2H2 and CO2 adsorption properties.
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Catalytic N-Si coupling as a vehicle for silane dehydrocoupling via [small alpha]-silylene elimination

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Dalton Trans., 2018, 47,2138-2142
DOI: 10.1039/C7DT04507G, Communication
Karla A. Erickson, Michael P. Cibuzar, Neil T. Mucha, Rory Waterman
Zirconium compounds appear to promote the liberation of silylene fragments via an N-Si coupling event.
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Water-soluble transition metal complexes of ruthenium(II), osmium(II), rhodium(III) and iridium(III) with chelating N-heterocyclic carbene ligands in hydrogenation and transfer hydrogenation catalysis

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Dalton Trans., 2018, 47,2318-2329
DOI: 10.1039/C7DT04684G, Paper
Esther Bayon Castanon, Marlene Kaposi, Robert M. Reich, Fritz E. Kuhn
The synthesis of novel Ru(II), Os(II), Rh(III) and Ir(III) mono-N-heterocyclic carbene (NHC) complexes and their application in hydrogenation catalysis is reported.
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