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RSC - Chem. Soc. Rev. latest articles



RSC - Chem. Soc. Rev. latest articles



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Copyright: Copyright (c) The Royal Society of Chemistry
 



Iminium and enamine catalysis in enantioselective photochemical reactions

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00509A, Tutorial Review
(image) Open Access
You-Quan Zou, Fabian M. Hormann, Thorsten Bach
The rapidly growing area of iminium and enamine catalysis in enantioselective photochemistry is reviewed, with an emphasis on catalytic modes and reaction types.
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Dendrimers in combination with natural products and analogues as anti-cancer agents

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Chem. Soc. Rev., 2018, Advance Article
DOI: 10.1039/C7CS00550D, Review Article
Serge Mignani, Joao Rodrigues, Helena Tomas, Maria Zablocka, Xiangyang Shi, Anne-Marie Caminade, Jean-Pierre Majoral
Overview of the use of dendrimers in combination with encapsulated and conjugated natural products and analogues as anti-cancer agents.
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Correction: Two-dimensional boron: structures, properties and applications
Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS90120H, Correction
(image) Open Access
Zhuhua Zhang, Evgeni S. Penev, Boris I. Yakobson
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Molecular spin qudits for quantum algorithms

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C5CS00933B, Review Article
Eufemio Moreno-Pineda, Clement Godfrin, Franck Balestro, Wolfgang Wernsdorfer, Mario Ruben
Molecules are promising building blocks for Quantum information processing. Herein we describe how a molecular multilevel nuclear spin qubit (or qudit, where d = 4), known as TbPc2, showing all necessary requirements to perform as a molecular hardware platform with a first generation of molecular devices enabling even quantum algorithm operations.
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Recent advances in quantum scattering calculations on polyatomic bimolecular reactions

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00526A, Review Article
Bina Fu, Xiao Shan, Dong H. Zhang, David C. Clary
This review surveys quantum scattering calculations on chemical reactions of polyatomic molecules in the gas phase published in the last ten years.
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Covalent post-assembly modification in metallosupramolecular chemistry

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C6CS00907G, Review Article
Derrick A. Roberts, Ben S. Pilgrim, Jonathan R. Nitschke
This review examines the growing variety of covalent reactions used to achieve the post-assembly modification of self-assembled metallosupramolecular complexes.
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Imaging the dynamics of ion-molecule reactions

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00623C, Review Article
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Eduardo Carrascosa, Jennifer Meyer, Roland Wester
A range of ion-molecule reactions have been studied in the last years using the crossed-beam ion imaging technique, from charge transfer and proton transfer to nucleophilic substitution and elimination.
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Phase separation in organic aerosol

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C6CS00783J, Tutorial Review
Miriam Arak Freedman
Liquid-liquid phase separation is prevalent in aerosol particles composed of organic compounds and salts and may impact aerosol climate effects.
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3D printing in chemical engineering and catalytic technology: structured catalysts, mixers and reactors

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00631D, Review Article
Cesar Parra-Cabrera, Clement Achille, Simon Kuhn, Rob Ameloot
This review highlights the research using 3D printing and computational modeling as digital tools for the design and fabrication of reactors and structured catalysts.
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Correction: Selective photocatalysis of lignin-inspired chemicals by integrating hybrid nanocatalysis in microfluidic reactors
Chem. Soc. Rev., 2017, 46,7094-7094
DOI: 10.1039/C7CS90108A, Correction
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Juan Carlos Colmenares, Rajender S. Varma, Vaishakh Nair
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Two-dimensional boron: structures, properties and applications

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Chem. Soc. Rev., 2017, 46,6746-6763
DOI: 10.1039/C7CS00261K, Review Article
Zhuhua Zhang, Evgeni S. Penev, Boris I. Yakobson
This review highlights the power of theory in pursuit of two-dimensional boron and presents its versatile properties and prospects for applications.
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Selective photocatalysis of lignin-inspired chemicals by integrating hybrid nanocatalysis in microfluidic reactors

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Chem. Soc. Rev., 2017, 46,6675-6686
DOI: 10.1039/C7CS00257B, Tutorial Review
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Juan Carlos Colmenares, Rajender S. Varma, Vaishakh Nair
In an ideal symbiosis of nanophotocatalysis and microflow chemistry, this tutorial review delineates a micro-highway decorated with semiconductor-based photocatalytic thin layers for the selective transformations of lignin-based chemicals to high-value organic products.
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Channel-facilitated molecule and ion transport across polymer composite membranes

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Chem. Soc. Rev., 2017, 46,6725-6745
DOI: 10.1039/C5CS00906E, Tutorial Review
Li Cao, Xueyi He, Zhongyi Jiang, Xueqin Li, Yifan Li, Yanxiong Ren, Leixin Yang, Hong Wu
This tutorial review highlights transport channels within polymer composite membranes and focuses on the regulation of channel microenvironments through bio-inspiration.
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Versatile design and synthesis of nano-barcodes

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Chem. Soc. Rev., 2017, 46,7054-7093
DOI: 10.1039/C7CS00271H, Review Article
Swati Shikha, Thoriq Salafi, Jinting Cheng, Yong Zhang
This review provides a critical discussion on the versatile designing and usage of nano-barcodes for various existing and emerging applications.
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Supramolecular chemotherapy based on host-guest molecular recognition: a novel strategy in the battle against cancer with a bright future

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Chem. Soc. Rev., 2017, 46,7021-7053
DOI: 10.1039/C6CS00898D, Review Article
Jiong Zhou, Guocan Yu, Feihe Huang
This review highlights the progress of supramolecular chemotherapy in cancer treatment based on host-guest interactions and provides guidance on the design of new targeting supramolecular chemotherapy combining diagnostic and therapeutic functions.
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Recent advances in nanomaterials for water protection and monitoring

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Chem. Soc. Rev., 2017, 46,6946-7020
DOI: 10.1039/C6CS00921B, Review Article
Rasel Das, Chad D. Vecitis, Agnes Schulze, Bin Cao, Ahmad Fauzi Ismail, Xianbo Lu, Jiping Chen, Seeram Ramakrishna
Nanomaterials (NMs) for adsorption, catalysis, separation, and disinfection are scrutinized. NMs-based sensor technologies and environmental transformations of NMs are highlighted.
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Emerging crystalline porous materials as a multifunctional platform for electrochemical energy storage

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Chem. Soc. Rev., 2017, 46,6927-6945
DOI: 10.1039/C7CS00283A, Review Article
Junwen Zhou, Bo Wang
This review highlights the functions of metal-organic frameworks and covalent-organic frameworks in batteries and supercapacitors.
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Light-driven micro/nanomotors: from fundamentals to applications

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Chem. Soc. Rev., 2017, 46,6905-6926
DOI: 10.1039/C7CS00516D, Review Article
Leilei Xu, Fangzhi Mou, Haotian Gong, Ming Luo, Jianguo Guan
This review summarizes the recent advances in light-driven micro/nanomotors and highlights the challenges and perspectives toward environmental, biomedical and micro/nanoengineering applications.
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Two-dimensional nanomaterial-based field-effect transistors for chemical and biological sensing

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Chem. Soc. Rev., 2017, 46,6872-6904
DOI: 10.1039/C6CS00827E, Review Article
Shun Mao, Jingbo Chang, Haihui Pu, Ganhua Lu, Qiyuan He, Hua Zhang, Junhong Chen
This review highlights the recent progress in graphene-, 2D transition metal dichalcogenide-, and 2D black phosphorus-based FET sensors for detecting gases, biomolecules, and water contaminants.
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Environmental performance of bio-based and biodegradable plastics: the road ahead

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Chem. Soc. Rev., 2017, 46,6855-6871
DOI: 10.1039/C7CS00149E, Review Article
Scott Lambert, Martin Wagner
This review provides a critical discussion as to the future direction of plastic materials, including balancing factors such as biodegradability and longevity, effects of additive compounds, feedstock developments, and environmental considerations.
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Universal analytical modeling of plasmonic nanoparticles

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Chem. Soc. Rev., 2017, 46,6710-6724
DOI: 10.1039/C6CS00919K, Tutorial Review
Renwen Yu, Luis M. Liz-Marzan, F. Javier Garcia de Abajo
Analytical expressions are applied to calculate the plasmonic spectra of nanoparticles with arbitrary morphology, in excellent agreement with experimental data.
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The difficult search for organocerium(IV) compounds

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Chem. Soc. Rev., 2017, 46,6697-6709
DOI: 10.1039/C7CS00147A, Tutorial Review
Reiner Anwander, Michael Dolg, Frank T. Edelmann
This Tutorial Review provides an overview of the historic and current development of the organometallic chemistry of cerium in its oxidation state 4+.
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New insights and perspectives into biological materials for flexible electronics

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Chem. Soc. Rev., 2017, 46,6764-6815
DOI: 10.1039/C7CS00278E, Review Article
Lili Wang, Di Chen, Kai Jiang, Guozhen Shen
Materials based on biological materials are becoming increasingly competitive and are likely to be critical components in flexible electronic devices.
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Latest advances in supercapacitors: from new electrode materials to novel device designs

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Chem. Soc. Rev., 2017, 46,6816-6854
DOI: 10.1039/C7CS00205J, Review Article
Faxing Wang, Xiongwei Wu, Xinhai Yuan, Zaichun Liu, Yi Zhang, Lijun Fu, Yusong Zhu, Qingming Zhou, Yuping Wu, Wei Huang
A comprehensive overview of the state-of-the-art progress toward mechanisms, new materials, and novel device designs for supercapacitors is provided. Further directions are also pointed out.
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Multiplexed photoluminescent sensors: towards improved disease diagnostics

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Chem. Soc. Rev., 2017, 46,6687-6696
DOI: 10.1039/C6CS00778C, Tutorial Review
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Xiao-Peng He, Xi-Le Hu, Tony D. James, Juyoung Yoon, He Tian
This tutorial review highlights the development of multiplexed photoluminescent sensors which can simultaneously detect multiple and diverse biomarkers that exist in a homogenous solution or a single cell, accelerating the progress towards precise disease diagnostics.
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[small alpha]-Substituted vinyl azides: an emerging functionalized alkene

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00017K, Review Article
Junkai Fu, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi
Vinyl azides are highly versatile synthons that provide access to numerous N-heterocycles and other functional groups.
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Control of electro-chemical processes using energy harvesting materials and devices

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00387K, Review Article
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Yan Zhang, Mengying Xie, Vana Adamaki, Hamideh Khanbareh, Chris R. Bowen
A detailed overview of pyro-electric, piezo-electric, tribo-electric, flexo-electric thermo-electric and photovoltaic charge generation mechanisms which are used to control electro-chemical reactions.
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Fluorescent probes for the simultaneous detection of multiple analytes in biology

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00528H, Review Article
Jacek L. Kolanowski, Fei Liu, Elizabeth J. New
This review identifies and discusses fluorescent sensors that are capable of simultaneously reporting on the presence of two analytes for biological application.
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Non-noble metal-catalysed carbonylative transformations

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00529F, Review Article
Yahui Li, Yuya Hu, Xiao-Feng Wu
The main achievements on non-noble metal (Mn, Fe, Cu, Co, Ni) catalysed carbonylative transformations have been summarized and discussed.
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Recent progress in two-dimensional inorganic quantum dots

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Chem. Soc. Rev., 2018, Advance Article
DOI: 10.1039/C7CS00500H, Review Article
Yuanhong Xu, Xiaoxia Wang, Wen Ling Zhang, Fan Lv, Shaojun Guo
This review critically summarizes recent progress in the categories, synthetic routes, properties, functionalization and applications of 2D materials-based quantum dots (QDs).
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Chemistry of mammalian metallothioneins and their interaction with amyloidogenic peptides and proteins

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00448F, Tutorial Review
Elena Atrian-Blasco, Alice Santoro, Dean L. Pountney, Gabriele Meloni, Christelle Hureau, Peter Faller
Tutorial focusing on the chemistry of mammalian metallothioneins, important to understand its biological functions in zinc and copper metabolism, detoxification and oxidative stress.
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An integrative omics perspective for the analysis of chemical signals in ecological interactions

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00368D, Tutorial Review
A. E. Brunetti, F. Carnevale Neto, M. C. Vera, C. Taboada, D. P. Pavarini, A. Bauermeister, N. P. Lopes
All living organisms emit, detect, and respond to chemical stimuli, thus creating an almost limitless number of interactions by means of chemical signals.
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Magnetic functionalities in MOFs: from the framework to the pore

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Chem. Soc. Rev., 2018, Advance Article
DOI: 10.1039/C7CS00653E, Review Article
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Guillermo Minguez Espallargas, Eugenio Coronado
This review covers the incorporation of different magnetic phenomena into MOFs, either in the framework or through the encapsulation of functional species in the pores.
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Recent progress in the assembly of nanodevices and van der Waals heterostructures by deterministic placement of 2D materials

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00556C, Tutorial Review
Riccardo Frisenda, Efren Navarro-Moratalla, Patricia Gant, David Perez De Lara, Pablo Jarillo-Herrero, Roman V. Gorbachev, Andres Castellanos-Gomez
Designer heterostructures can be assembled layer-by-layer with unmatched precision thanks to the recently developed deterministic placement methods to transfer two-dimensional materials.
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Ligands for f-element extraction used in the nuclear fuel cycle

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00574A, Review Article
Andrea Leoncini, Jurriaan Huskens, Willem Verboom
This review describes the latest advances regarding the development, modification and application of suitable ligands for the liquid-liquid extraction of actinides and lanthanides from nuclear waste.
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Metal-organic frameworks based membranes for liquid separation

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00575J, Tutorial Review
Xin Li, Yuxin Liu, Jing Wang, Jorge Gascon, Jiansheng Li, Bart Van der Bruggen
This Tutorial Review highlights the achievements in the rational design and the latest applications of MOF-based membranes in liquid separation.
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Biomimetics: reconstitution of low-density lipoprotein for targeted drug delivery and related theranostic applications

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00492C, Tutorial Review
Chunlei Zhu, Younan Xia
This tutorial review introduces the concept of reconstituting low-density lipoprotein for the targeted delivery of different types of theranostic agents.
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Exploring the emergence of complexity using synthetic replicators

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00123A, Review Article
Tamara Kosikova, Douglas Philp
The interplay of auto- and crosscatalysis, network connectivity and non-equilibrium conditions can generate complex functions in networks of synthetic replicators.
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Quinone-based fluorophores for imaging biological processes

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00553A, Tutorial Review
Gleiston G. Dias, Aaron King, Fabio de Moliner, Marc Vendrell, Eufranio N. da Silva Junior
This tutorial review covers recent advances in the design, synthesis and application of quinone-based fluorescent agents for visualizing specific processes in multiple biological systems, from cells to tissues and complex organisms in vivo.
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Correction: The physics and chemistry of graphene-on-surfaces
Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS90114C, Correction
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Guoke Zhao, Xinming Li, Meirong Huang, Zhen Zhen, Yujia Zhong, Qiao Chen, Xuanliang Zhao, Yijia He, Ruirui Hu, Tingting Yang, Rujing Zhang, Changli Li, Jing Kong, Jian-Bin Xu, Rodney S. Ruoff, Hongwei Zhu
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Secondary metabolism in the lichen symbiosis

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00431A, Review Article
Mark J. Calcott, David F. Ackerley, Allison Knight, Robert A. Keyzers, Jeremy G. Owen
Lichens, which are defined by a symbiosis between a mycobiont (fungal partner) and a photobiont (photoautotrophic partner), are in fact complex assemblages of microorganisms that constitute a largely untapped source of bioactive secondary metabolites.
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Design and chemical synthesis of eukaryotic chromosomes

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00208D, Tutorial Review
Ze-Xiong Xie, Duo Liu, Bing-Zhi Li, Meng Zhao, Bo-Xuan Zeng, Yi Wu, Yue Shen, Tao Lin, Ping Yang, Junbiao Dai, Yizhi Cai, Huanming Yang, Ying-Jin Yuan
We reviewed the design, building, testing and debugging technologies and methodologies for synthesizing designer eukaryotic chromosomes and forecasted their applications.
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Recent advances in droplet wetting and evaporation

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Chem. Soc. Rev., 2018, Advance Article
DOI: 10.1039/C6CS00902F, Review Article
D. Brutin, V. Starov
Wetting and evaporation of a simple sessile droplet is a very complex problem involving strongly coupled physics.
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Advancing porphyrin's biomedical utility via supramolecular chemistry

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Chem. Soc. Rev., 2017, 46,6433-6469
DOI: 10.1039/C7CS00525C, Tutorial Review
M. A. Rajora, J. W. H. Lou, G. Zheng
Enhancing existing porphyrin functionality and introducing new capabilities via supramolecular chemistry.
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Supramolecular medicine

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Chem. Soc. Rev., 2017, 46,6430-6432
DOI: 10.1039/C7CS90102J, Editorial
Honggang Cui, Bing Xu
Guest editors Honggang Cui and Bing Xu introduce the supramolecular medicine issue of Chemical Society Reviews. In a broader context, Supramolecular Medicine can be defined as the supramolecular formulation of diagnostic and therapeutic agents for the diagnosis, treatment, and prevention of disease.
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Guanidinium-based "molecular glues" for modulation of biomolecular functions

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Chem. Soc. Rev., 2017, 46,6480-6491
DOI: 10.1039/C7CS00647K, Tutorial Review
Rina Mogaki, P. K. Hashim, Kou Okuro, Takuzo Aida
This tutorial review highlights "molecular glues" designed for manipulation of biomolecular assemblies, drug delivery systems, and modulation of biomolecular functions.
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Self-assembling prodrugs

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Chem. Soc. Rev., 2017, 46,6638-6663
DOI: 10.1039/C7CS00521K, Review Article
Andrew G. Cheetham, Rami W. Chakroun, Wang Ma, Honggang Cui
Covalent modification of therapeutic compounds is a clinically proven strategy to devise prodrugs with enhanced treatment efficacies. Self-assembly of prodrugs expands the functional space of conventional prodrug design, providing a possible pathway to more effective therapies.
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From supramolecular polymers to multi-component biomaterials

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Chem. Soc. Rev., 2017, 46,6621-6637
DOI: 10.1039/C7CS00564D, Review Article
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Olga J. G. M. Goor, Simone I. S. Hendrikse, Patricia Y. W. Dankers, E. W. Meijer
This review features the translation of supramolecular fibers into elastomers and hydrogels for regenerative medicine.
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Synthetic polypeptides: from polymer design to supramolecular assembly and biomedical application

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Chem. Soc. Rev., 2017, 46,6570-6599
DOI: 10.1039/C7CS00460E, Review Article
Ziyuan Song, Zhiyuan Han, Shixian Lv, Chongyi Chen, Li Chen, Lichen Yin, Jianjun Cheng
This review highlights the recent advances in the chemical design, supramolecular assembly, and biomedical application of synthetic polypeptides from N-carboxyanhydrides.
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Molecular engineering solutions for therapeutic peptide delivery

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Chem. Soc. Rev., 2017, 46,6553-6569
DOI: 10.1039/C7CS00536A, Review Article
Handan Acar, Jeffrey M. Ting, Samanvaya Srivastava, James L. LaBelle, Matthew V. Tirrell
This review discusses self-assembled vehicles as nanoparticles to carry and protect therapeutic peptides through their journeys in the body.
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Supramolecular catalysis and dynamic assemblies for medicine

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Chem. Soc. Rev., 2017, 46,6470-6479
DOI: 10.1039/C7CS00472A, Tutorial Review
Zhaoqianqi Feng, Tengfei Zhang, Huaimin Wang, Bing Xu
This review provides new insights into supramolecular catalysis and dynamic regulation of molecular assemblies for biomedical applications.
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Drug delivery by supramolecular design

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Chem. Soc. Rev., 2017, 46,6600-6620
DOI: 10.1039/C7CS00391A, Review Article
Matthew J. Webber, Robert Langer
Principles rooted in supramolecular chemistry have empowered new and highly functional therapeutics and drug delivery devices. This general approach offers elegant tools rooted in molecular and materials engineered to address the many challenges faced in treating disease.
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Spatiotemporal hydrogel biomaterials for regenerative medicine

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Chem. Soc. Rev., 2017, 46,6532-6552
DOI: 10.1039/C7CS00445A, Review Article
Tobin E. Brown, Kristi S. Anseth
This review highlights recent efforts in using photochemistry to exert dynamic control over the properties of hydrogel biomaterials.
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Implications of peptide assemblies in amyloid diseases

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Chem. Soc. Rev., 2017, 46,6492-6531
DOI: 10.1039/C7CS00372B, Review Article
Pu Chun Ke, Marc-Antonie Sani, Feng Ding, Aleksandr Kakinen, Ibrahim Javed, Frances Separovic, Thomas P. Davis, Raffaele Mezzenga
We highlight the role of molecular self-assembly in eliciting the mesoscopic and pathological properties of amyloid proteins. This knowledge is pivotal for the development of theranostics against amyloid diseases.
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Biomass-derived nanostructured carbons and their composites as anode materials for lithium ion batteries

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C6CS00639F, Tutorial Review
Wenyu Long, Baizeng Fang, Anna Ignaszak, Zhuangzhi Wu, Yan-Jie Wang, David Wilkinson
This review focuses on the derivation of nanostructured carbons and their composite materials from biomass materials for lithium ion battery anodes.
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Access to the meta position of arenes through transition metal catalysed C-H bond functionalisation: a focus on metals other than palladium

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00637C, Review Article
Madalina T. Mihai, Georgi R. Genov, Robert J. Phipps
The elaboration of simple arenes in order to access more complex substitution patterns is a crucial endeavor for synthetic chemists, given the central role that aromatic rings play in all manner of important molecules.
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Engineering of inorganic nanoparticles as magnetic resonance imaging contrast agents

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00316A, Review Article
Dalong Ni, Wenbo Bu, Emily B. Ehlerding, Weibo Cai, Jianlin Shi
This review focuses on the design principles of inorganic nanoparticles to engineer high-performance contrast agents for magnetic resonance imaging.
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Fluorogenic reaction-based prodrug conjugates as targeted cancer theranostics

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Chem. Soc. Rev., 2017, Advance Article
DOI: 10.1039/C7CS00557A, Tutorial Review
Min Hee Lee, Amit Sharma, Min Jung Chang, Jinju Lee, Subin Son, Jonathan L. Sessler, Chulhun Kang, Jong Seung Kim
This Tutorial Review will describe various fluorogenic reaction-based prodrug strategies used for targeted theranostic drug delivery.
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